Pregled bibliografske jedinice broj: 998806
Theory of square wave voltammetry of two reversible electrode reactions connected by the reversible chemical reaction
Theory of square wave voltammetry of two reversible electrode reactions connected by the reversible chemical reaction // To Chemistry Journal, 2 (2019), 1; 142-153 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 998806 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Theory of square wave voltammetry of two reversible electrode reactions connected by the reversible chemical reaction
Autori
Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj
Izvornik
To Chemistry Journal (2581-7507) 2
(2019), 1;
142-153
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
ECE mechanism ; square wave voltammetry ; theory ; kinetics ; equilibrium conditions.
Sažetak
A theory of ECE mechanism that consists of two reversible electrode reactions coupled by kinetically controlled reversible chemical reaction is developed for square wave voltammetry on stationary planar electrode. The influences of frequency and the concentration of chemical reactant X- on the responses are investigated for thermodynamically stable intermediate. The limits of three types of responses are calculated and the formula for the estimation of the forward rate constant of chemical reaction is proposed.
Izvorni jezik
Engleski
