Naslov
The removal of neonicotinoid insecticide imidacloprid in an annular photoreactor

Autori
Babić, Kristina ; Tomašić, Vesna

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
8th International Conference WATER FOR ALL / Habuda Stanić, Mirna - Osijek : Prehrambeno tehnološki fakultet Sveučilišta Josipa Jurja Strossmayera u Osijeku, 2019, 72-72

ISBN
978-953-7005-59-7

Skup
8. međunarodni znanstveno-stručni skup: Voda za sve = 8th International Scientific and Professional Conference: Water for all

Mjesto i datum
Osijek, Hrvatska, 21.01.2019. - 22.01.2019

Vrsta sudjelovanja
Poster

Vrsta recenzije
Recenziran

Ključne riječi
heterogeneous photocatalysis ; neonicotinoid insecticides ; imidacloprid ; annular reactor

Sažetak
Heterogeneous photocatalysis has recently attracted an increasing interest of scientists and experts who deal with the waste water and air treatment. An important area of application is removal of persistent organic pollutants, which can not be easily destroyed by conventional methods. Among these pollutants are neonicotinoid insecticides, which are widely used all over the world and currently are included in the watch list of substances of the European Commission within the Water Framework Directive. Therefore, there is a need to study their influence on the environment and to develop appropriate technologies for their removal. In this work, the photolytic and photocatalytic degradation of neonicotinoid insecticide imidacloprid in an annular photoreactor with recirculation under different working conditions (irradiation source, pH, type and concentration of the catalyst) was studied. The photolytic degradation was examined using lamps that emit UVA, UVC and sun light. The photocatalytic experiments in the suspension involved the use of commercial titanium dioxide (TiO2 P25, Degussa/Evonik), commercial TiO2 P25 pre-treated with UVC irradiation and nitrogen-doped TiO2 (produced by Cinkarna Celje). The catalysts were characterized using XRD, UV/Vis-DRS, BET and SEM/EDX analysis. The most efficient photocatalyst was then immobilized on the glass woving fibre, using peroxotitanic acid as a binder. The degree of imidacloprid degradation was determined using high performance liquid chromatography (HPLC). According to the obtained results, UVC-treated TiO2 showed the best efficiency among the examined catalysts in the slurry reactor using lamp that emit sun irradiation. The degradation rate increases with the increase in the catalyst concentration. The immobilized UVC-treated catalyst gave satisfying results in terms of stability, activity and reuse.

Izvorni jezik
Engleski

Znanstvena područja
Kemijsko inženjerstvo

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