Naslov
Catalyst degradation diagnostics of proton exchange membrane fuel cells using electrochemical impedance spectroscopy

Autori
Pivac, Ivan ; Bezmalinović, Dario ; Barbir, Frano

Izvornik
International journal of hydrogen energy (0360-3199) 43 (2018), 29; 13512-13520

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
catalyst degradation ; accelerated stress test ; electrochemical impedance spectroscopy ; electrical equivalent circuit model ; inductive loop ; low-frequency intercept

Sažetak
A previously validated equivalent circuit model, in which two resonant circuits were inserted to represent the processes in the catalyst layers, is applied to fit the electrochemical impedance spectroscopy results of a single proton exchange membrane fuel cell exposed to accelerated stress test targeting catalyst degradation. The simulation results of the applied equivalent circuit model show very good agreement with the experimental data. The applied model is able to extract contributions of each of the model elements to the cell degradation. The obtained results indicate that the cathode catalyst layer resonant loop parameters, together with the cathode charge transfer resistance and cathode double-layer capacitance, change the most during the accelerated stress test. If each of the elements of the cathode resonant loop can be associated with physical processes inside the catalyst layer, the model may be used to give more insight into the degradation effects on functioning of the catalyst layer. From the conducted electrochemical impedance spectroscopy analysis, it seems that the low-frequency intercept in Nyquist plot shows the most significant change with degradation, so it may be used directly as a sufficient indicator of fuel cell performance degradation due to catalyst layer degradation.

Izvorni jezik
Engleski

Znanstvena područja
Kemijsko inženjerstvo, Strojarstvo

POVEZANOST RADA