Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks

Fidelli, Athena M.; Karadeniz, Bahar; Howarth, Ashlee J.; Huskić, Igor; Germann, Luzia S.; Halasz, Ivan; Etter, Martin; Moon, Su-Young; Dinnebier, Robert E.; Stilinović, Vladimir; Farha, Omar K.; Friščić, Tomislav; Užarević, Krunoslav

doi:10.1039/c8cc03189d

Pregled bibliografske jedinice broj: 940458

Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks

Fidelli, Athena M.; Karadeniz, Bahar; Howarth, Ashlee J.; Huskić, Igor; Germann, Luzia S.; Halasz, Ivan; Etter, Martin; Moon, Su-Young; Dinnebier, Robert E.; Stilinović, Vladimir et al.

Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks // Chemical communications, 54 (2018), 51; 6999-7002 doi:10.1039/c8cc03189d (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 940458 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Green and rapid mechanosynthesis of high-porosity NU- and UiO-type metal–organic frameworks

Autori
Fidelli, Athena M. ; Karadeniz, Bahar ; Howarth, Ashlee J. ; Huskić, Igor ; Germann, Luzia S. ; Halasz, Ivan ; Etter, Martin ; Moon, Su-Young ; Dinnebier, Robert E. ; Stilinović, Vladimir ; Farha, Omar K. ; Friščić, Tomislav ; Užarević, Krunoslav

Izvornik
Chemical communications (1359-7345) 54 (2018), 51; 6999-7002

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
mechanochemical synthesis ; MOF materials ; NU-901 ; UiO-67

Sažetak
The use of a dodecanuclear zirconium acetate cluster as a precursor enables the rapid, clean mechanochemical synthesis of high-microporosity metal–organic frameworks NU-901 and UiO-67, with surface areas up to 2250 m2 g−1. Real-time X-ray diffraction monitoring reveals that mechanochemical reactions involving the conventional hexanuclear zirconium methacrylate precursor are hindered by the formation of an inert intermediate, which does not appear when using the dodecanuclear acetate cluster as a reactant.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA

Projekti:
HRZZ-UIP-2014-09-4744 - Mehanokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala (MECHANOCONTROL) (Užarević, Krunoslav, HRZZ - 2014-09) ( CroRIS)

Ustanove:
Institut "Ruđer Bošković", Zagreb,
Prirodoslovno-matematički fakultet, Zagreb

Profili:

Vladimir Stilinović (autor)