Pregled bibliografske jedinice broj: 938672
Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles
Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles // Croatica chemica acta, 90 (2017), 4; 637-643 doi:10.5562/cca3248 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 938672 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Synthesis and Anion Binding Assessment of Novel Adamantane Amidopyrroles
Autori
Alešković, Marija ; Glavaš, Mladena ; Šekutor, Marina ; Mlinarić-Majerski, Kata
Izvornik
Croatica chemica acta (0011-1643) 90
(2017), 4;
637-643
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
anion receptors, adamantane amidopyrroles, binding assessment
Sažetak
Two new adamantane anion receptors with amidopyrrole side arms were prepared and their anion binding ability in DMSO solutions with TBA salts (Cl–, AcO– and H2PO4–) was investigated by UV/Vis spectroscopy. After calculating the corresponding association constants of receptor-anion complexes, it became apparent that only one amidopyrrole side arm was engaged in complexation. These experimental findings were rationalized using computational tools and the binding mode was proposed. In addition to the found 1 : 1 stoichiometry, we showed that the studied receptors bind oxo-anions (H2PO4– and AcO–) more strongly than spherical halogenide (Cl–) anions.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982933-2911 - Kavezasti spojevi: ugradbene jedinice u molekularnim sustavima (Majerski, Kata, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
