Naslov
Solid state transformations of copper(II) complexes with 1, 10-phenantroline and L-serine

Autori
Vušak, Darko ; Milić, Dalibor ; Prugovečki, Biserka ; Matković-Čalogović, Dubravka

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Solid-state science and research : book of abstracts / Juribašić-Kulcsár, Marina ; Halasz, Ivan - Zagreb : Institut Ruđer Bošković, 2017, 110-110

ISBN
978-953-7941-15-4

Skup
Solid-State Science & Research

Mjesto i datum
Zagreb, Hrvatska, 28.06.2017. - 30.06.2017

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
solvent exchange ; porous structures ; supramolecular chemistry ; solid-state transformations

Sažetak
Copper(II) complexes with heterocyclic bases and amino acids are extensively researched as model systems for proteins[1]. They possess various biological activities[2]. Considering the structures of the title ligands, their complexes may form many different motifs of hydrogen bonds and also stack through π- interactions. In our research we have synthesized and structurally characterized six different solvates of copper(II) complexes with 1, 10- phenantroline (phen) and L- serine (L- ser) in the water/methanol system: [Cu(L-ser) (H2O) (phen)]2SO4·nH2O (n = 4, 6 and 10), [Cu(L-ser) (H2O)(phen)][Cu(L-ser)(CH3OH) (phen)]SO4·3H2O·CH3OH, [Cu(L-ser)(CH3OH) (phen)]2SO4·mCH3OH (m = 2 and 2.5). Compounds showed high sensitivity toward the amount of water and methanol in the surrounding solution and humidity of the atmosphere. We have performed experiments in different surroundings and successfully performed interconversion of the solvates in the solid state.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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