Naslov
Nitranilic acid as a bridging ligand for construction of novel coordination polymers

Autori
Milašinović, Valentina ; Molčanov, Krešimir

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Solid-State Science & Research : Book of Abstracts and Programme / Juribašić Kulcsar, Marina ; Halasz, Ivan - Zagreb : Institut Ruđer Bošković, 2017, 76-76

ISBN
978-953-7941-15-4

Skup
Solid State Science and Research Meeting

Mjesto i datum
Zagreb, Hrvatska, 28.06.2017. - 30.06.2017

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
coordination polymers ; quinone ; nitranilic acid

Sažetak
Nitranilic acid (2, 5-dihydroxy-3, 5-dinitroquinone, NA) is a quinoid compound capable of acting as a bridging bis(bidentate) ligand analogous to other substituted 2, 5-dihydroxyquinones (anilic acids) and the oxalate dianion. However, it has been surprisingly little studied and only a few of its metal complexes have been known. We have prepared and structurally characterised a series of novel coordination polymers of nitranilic acid with different topologies. Compounds [CoNA(H2O)2]n and [CuNA(H2O)2]n are isostructural and are 1D zig-zag polymers analogous to similar complexes of chloranilic acid. Anionic polymer [AgNA]-n crystallises as a salt with dimethylammonium cation and displays a novel 1D motive of double chains. Complex [Ag2NA]n has a 3D network. This study shows that the nitranilic acid has a great potential for design of coordination polymers or metal-organic frameworks.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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