Naslov
Nitranilic acid - a novel ligand for construction of coordination polymers

Autori
Milašinović, Valentina ; Molčanov, Krešimir

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Twenty-fifth Slovenian-Croatian Crystallographic Meeting : Book of Abstracts and Programme / - , 2017, 76-76

Skup
Twenty-fifth Slovenian-Croatian Crystallographic Meeting

Mjesto i datum
Ljubljana, Slovenija, 14.06.2017. - 18.06.2017

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Nije recenziran

Ključne riječi
Nitranilic acid ; coordination polymers

Sažetak
Nitranilic acid (2, 5-dihydroxy-3, 5-dinitroquinone, NA) is a quinoid compound capable of acting as a bridging bis(bidentate) ligand. However, it has been surprisingly little studied and only a few of its metal complexes have been known. We have prepared and structurally characterised four novel coordination polymers of nitranilic acid with different topologies. Compounds [CoNA(H2O)2]n and [CuNA(H2O)2]n are isostructural and are 1D zig-zag polymers analogous to similar complexes of chloranilic acid. Anionic polymer [AgNA]-n crystallises as a salt with dimethylammonium cation and displays a novel 1D motive of double chains. Complex [Ag2NA]n has a 3D network. This study shows that the nitranilic acid has a great potential for design of coordination polymers or metal-organic frameworks.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA