Naslov
Effect of Different Pd(II) Precursors on Rates of Solid-State C–H Bond Activation

Autori
Bjelopetrović, Alen ; Lukin, Stipe ; Halasz, Ivan ; Užarević, Krunoslav ; Juribašić Kulcsar, Marina ; Ćurić, Manda

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
XXII EUCOMC2017 / - , 2017, P22-P22

Skup
EuCheMS International Organometallic Conference XXII, EUCOMC2017

Mjesto i datum
Amsterdam, Nizozemska, 09.07.2017. - 13.07.2017

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
cyclopalladation, solid-state synthesis, azobenzene, Pd precursors

Sažetak
While the C–H bond activation by Pd(II) compounds is widely explored in solution, investigations in solid-state are limited in spite of the fact that the solid-state methods such as ball milling and accelerating aging, have been evaluated as a valuable alternative to the traditional synthetic methods in solution. Here we describe mechanochemical and vapour-induced C–H bond activation of 4-chloro-4’-(N, N-dimethylamino)azobenzene with various Pd(II) compounds (Figure 1). In situ Raman monitoring of solid-state processes reveals a strong influence of different Pd(II) precursors on the rate of azobenzene C–H bond(s) activation. Moreover, the formation of final products, containing either one or two Pd–C σ bonds, depends on applied solid-state method and Pd(II) compound.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA