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Pregled bibliografske jedinice broj: 872353

Enantiopure (9-anthryl)(2-piperidyl)- and (9- anthryl)(2- pyridyl)methanols - Their use as chiral modifiers for heterogeneous hydrogenation of keto esters over Pt/Al2O3

Solladie-Cavallo, Arlette; Marsol, Claire; Azyat, Khalid; Roje, Marin; Welch, Christopher; Chilenski, Jennifer; Taillasson, Philippe; D'Orchymont, Hugues
Enantiopure (9-anthryl)(2-piperidyl)- and (9- anthryl)(2- pyridyl)methanols - Their use as chiral modifiers for heterogeneous hydrogenation of keto esters over Pt/Al2O3 // European journal of organic chemistry, 5 (2007), 826-830 doi:10.1002/ejoc.200600734 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 872353 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Enantiopure (9-anthryl)(2-piperidyl)- and (9- anthryl)(2- pyridyl)methanols - Their use as chiral modifiers for heterogeneous hydrogenation of keto esters over Pt/Al2O3

Autori
Solladie-Cavallo, Arlette ; Marsol, Claire ; Azyat, Khalid ; Roje, Marin ; Welch, Christopher ; Chilenski, Jennifer ; Taillasson, Philippe ; D'Orchymont, Hugues

Izvornik
European journal of organic chemistry (1434-193X) 5 (2007); 826-830

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
amino alcohols ; chiral resolution ; chiral modifiers ; hydrogenation

Sažetak
A route toward the synthesis of the erythro isomer of (9-anthryl)(2- piperidyl)methanol is presented as well as resolution and assignment of the structure (through NMR). The use of both the erythro and threo enantiopure isomers of this new amino alcohol, and its precursor [(9- anthryl)(2-pyridyl)methanol], as chiral modifiers for the Pt/Al2O3 hydrogenation of ethyl lactate showed that the erythro isomer is not necessarily the most efficient chiral modifier. This is probably because of the 9- anthryl group. The enantioselectivities that this compound provides are not, as one would expect, higher than those observed with the naphthyl group.

Izvorni jezik
Engleski

Znanstvena područja
Kemija



POVEZANOST RADA

Ustanove:
Institut "Ruđer Bošković", Zagreb

Profili:

Avatar Url Marin Roje (autor)

Poveznice na cjeloviti tekst rada:

doi onlinelibrary.wiley.com

Citiraj ovu publikaciju:

Solladie-Cavallo, Arlette; Marsol, Claire; Azyat, Khalid; Roje, Marin; Welch, Christopher; Chilenski, Jennifer; Taillasson, Philippe; D'Orchymont, Hugues
Enantiopure (9-anthryl)(2-piperidyl)- and (9- anthryl)(2- pyridyl)methanols - Their use as chiral modifiers for heterogeneous hydrogenation of keto esters over Pt/Al2O3 // European journal of organic chemistry, 5 (2007), 826-830 doi:10.1002/ejoc.200600734 (međunarodna recenzija, članak, znanstveni)
Solladie-Cavallo, A., Marsol, C., Azyat, K., Roje, M., Welch, C., Chilenski, J., Taillasson, P. & D'Orchymont, H. (2007) Enantiopure (9-anthryl)(2-piperidyl)- and (9- anthryl)(2- pyridyl)methanols - Their use as chiral modifiers for heterogeneous hydrogenation of keto esters over Pt/Al2O3. European journal of organic chemistry, 5, 826-830 doi:10.1002/ejoc.200600734.
@article{article, author = {Solladie-Cavallo, Arlette and Marsol, Claire and Azyat, Khalid and Roje, Marin and Welch, Christopher and Chilenski, Jennifer and Taillasson, Philippe and D'Orchymont, Hugues}, year = {2007}, pages = {826-830}, DOI = {10.1002/ejoc.200600734}, keywords = {amino alcohols, chiral resolution, chiral modifiers, hydrogenation}, journal = {European journal of organic chemistry}, doi = {10.1002/ejoc.200600734}, volume = {5}, issn = {1434-193X}, title = {Enantiopure (9-anthryl)(2-piperidyl)- and (9- anthryl)(2- pyridyl)methanols - Their use as chiral modifiers for heterogeneous hydrogenation of keto esters over Pt/Al2O3}, keyword = {amino alcohols, chiral resolution, chiral modifiers, hydrogenation} }
@article{article, author = {Solladie-Cavallo, Arlette and Marsol, Claire and Azyat, Khalid and Roje, Marin and Welch, Christopher and Chilenski, Jennifer and Taillasson, Philippe and D'Orchymont, Hugues}, year = {2007}, pages = {826-830}, DOI = {10.1002/ejoc.200600734}, keywords = {amino alcohols, chiral resolution, chiral modifiers, hydrogenation}, journal = {European journal of organic chemistry}, doi = {10.1002/ejoc.200600734}, volume = {5}, issn = {1434-193X}, title = {Enantiopure (9-anthryl)(2-piperidyl)- and (9- anthryl)(2- pyridyl)methanols - Their use as chiral modifiers for heterogeneous hydrogenation of keto esters over Pt/Al2O3}, keyword = {amino alcohols, chiral resolution, chiral modifiers, hydrogenation} }

Časopis indeksira:


  • Current Contents Connect (CCC)
  • Web of Science Core Collection (WoSCC)
    • Science Citation Index Expanded (SCI-EXP)
    • SCI-EXP, SSCI i/ili A&HCI
  • Scopus

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