Pregled bibliografske jedinice broj: 865655
Gas-Phase Synthesis and Structure of Wade-Type Ruthenium Carbonyl and Hydrido Carbonyl Clusters
Gas-Phase Synthesis and Structure of Wade-Type Ruthenium Carbonyl and Hydrido Carbonyl Clusters // Journal of Physical Chemistry A, 118 (2014), 37; 8356-8359 doi:10.1021/jp501242c (međunarodna recenzija, članak, znanstveni)
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Naslov
Gas-Phase Synthesis and Structure of Wade-Type Ruthenium Carbonyl and Hydrido Carbonyl Clusters
Autori
Lang, Sandra M. ; Förtig, Sandra U. ; Bernhardt, Thorsten M. ; Krstić, Marjan ; Bonačić-Koutecký Vlasta
Izvornik
Journal of Physical Chemistry A (1089-5639) 118
(2014), 37;
8356-8359
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
ruthenium carbonyl clusters, ruthenium hydrido carbonyl clusters, structures, experiments, DFT
Sažetak
The gas-phase reaction of size-selected Run+ (n = 4–6) clusters with CO in an ion trap yields only one specific ruthenium carbonyl complex for each cluster size, Ru4(CO)14+, Ru5(CO)16+, and Ru6(CO)18+. First-principles density functional theory calculations reveal structures for these hitherto unknown carbonyl compounds that are in perfect agreement with the geometries predicted by Wade’s electron counting rules. Furthermore, reactions with D2 show that for Ru4+ and Ru6+, CO molecules can be partially replaced by D2 to form hydrido carbonyl complexes while preserving the total ligand count corresponding to the Wade cluster sizes.
Izvorni jezik
Engleski
Znanstvena područja
Fizika, Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
