Pregled bibliografske jedinice broj: 840206
Two-step synthesis of monoterpenoid dioxinols exhibiting analgesic activity from isopulegol and benzaldehyde over heterogeneous catalysts
Two-step synthesis of monoterpenoid dioxinols exhibiting analgesic activity from isopulegol and benzaldehyde over heterogeneous catalysts // Catalysis today, 279 (2016), 1; 56-62 doi:10.1016/j.cattod.2016.03.046 (međunarodna recenzija, članak, znanstveni)
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Naslov
Two-step synthesis of monoterpenoid dioxinols exhibiting analgesic activity from isopulegol and benzaldehyde over heterogeneous catalysts
Autori
Stekrova, M. ; ... ; Maduna Valkaj, Karolina ; ... ; Kumar, Narendra ; ... ; Murzin, D.Y.
Izvornik
Catalysis today (0920-5861) 279
(2016), 1;
56-62
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Terpenoid ; Isomerization ; Zeolite ; Mesoporous material ; Isopulegol ; Benzaldehyde ; Benzodioxinols ; Prins cyclization
Sažetak
Benzodioxinols, compounds with 6-membered heterocycles containing two oxygen atoms, exhibit promising analgesic activity. In the current study, synthesis of dioxinol via two-step approach including Prins cyclization of isopulegol with benzaldehyde to tetrahydropyran and its ring-rearrangement to dioxinol was investigated. Different acidic and basic catalysts were studied in the second step and the highest selectivity toward dioxinol was achieved using mesoporous Ce-composite material.
Izvorni jezik
Engleski
Znanstvena područja
Kemijsko inženjerstvo
POVEZANOST RADA
Ustanove:
Fakultet kemijskog inženjerstva i tehnologije, Zagreb
Profili:
Karolina Maduna
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus