Pregled bibliografske jedinice broj: 832909
Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor
Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor // Chemical communications, 52 (2016), 88; 12960-12963 doi:10.1039/c6cc06062e (međunarodna recenzija, članak, znanstveni)
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Naslov
Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor
Autori
Monas, Andrea ; Užarević, Krunoslav ; Halasz, Ivan ; Juribašić Kulcsar, Marina ; Ćurić, Manda
Izvornik
Chemical communications (1359-7345) 52
(2016), 88;
12960-12963
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
C-H activation ; accelerated aging ; palladium ; azobenzene ; biothiol sensor
Sažetak
Room-temperature accelerated aging in the solid state has been applied for atom- and energy-efficient activation of either one or two C–H bonds of azobenzene and methyl orange by palladium(II) acetate. Organopalladium complexes are prepared in quantitative reactions without potentially harmful side products. Dicyclopalladated methyl orange is water-soluble and is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in buffered aqueous media.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
HRZZ-IP-2014-09-7984 - Zelena sinteza organopaladijevih foto-osjetljivih spojeva (GREENSENS) (Ćurić, Manda, HRZZ - 2014-09) ( CroRIS)
HRZZ-UIP-2014-09-4744 - Mehanokemijska reaktivnost pod kontroliranim uvjetima temperature i atmosfere za čišću sintezu funkcionalnih materijala (MECHANOCONTROL) (Užarević, Krunoslav, HRZZ - 2014-09) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Profili:
Ivan Halasz
(autor)
Marina Juribašić Kulcsar
(autor)
Manda Ćurić
(autor)
Krunoslav Užarević
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- Arts & Humanities Citation Index (A&HCI)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
- Nature Index