Pregled bibliografske jedinice broj: 830915
Influence of the phthalimide substituents on the photochemical reactivity in photodecarboxylation
Influence of the phthalimide substituents on the photochemical reactivity in photodecarboxylation // 5th HRSMC Photochemistry School "Photochemistry, Fundamentals and Applications"
Maastricht, 2016. (poster, međunarodna recenzija, sažetak, znanstveni)
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Naslov
Influence of the phthalimide substituents on the photochemical reactivity in photodecarboxylation
Autori
Mandić, Leo ; Mlinarić-Majerski, Kata ; Basarić, Nikola
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
5th HRSMC Photochemistry School "Photochemistry, Fundamentals and Applications"
/ - Maastricht, 2016
Skup
5th HRSMC Photochemistry School "Photochemistry, Fundamentals and Applications"
Mjesto i datum
Maastricht, Nizozemska, 27.08.2016. - 31.08.2016
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
photochemistry ; photodecarboxylation ; phthalimide
Sažetak
Photodecarboxylation has been intensively studied due to synthetic applications [1]. Moreover, phototoxicity of some nonsteroidal non-inflammatory drugs is a consequence of photodecarboxylation [2]. Photodecarboxylation can also be initiated by phthalimide in the triplet excited state in a role of an oxidizing agent in photoinduced electron transfer (PET) [3]. Photodecarboxylation study of compound 1a [4] and its isomers (2-5) [5] prompted us to synthesize new derivatives 1b-1g with different substituent at the position 4 of the phthalimide chromophore, and investigate their influence on the photochemical reactivity.
Izvorni jezik
Engleski
POVEZANOST RADA
Projekti:
HRZZ-IP-2014-09-6312 - Supramolekulska kontrola fotokemijskih reakcija eliminacije (SupraPhotoE) (Basarić, Nikola, HRZZ - 2014-09) ( CroRIS)