Naslov
Chiral Induction of Novel Ferrocene-Phosphine Ligands in Enantioselective Hydrogenation

Autori
Kokan, Zoran ; Opačak, Saša ; Kirin, Srećko I.

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Conference Abstract Book, p. 152. / - , 2016, 152-152

Skup
7th Annual Global Congress of Catalysis 2016 (GCC-2016)

Mjesto i datum
Goyang-si, Republika Koreja, 30.06.2016. - 02.07.2016

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
enantioselective catalysis ; phosphine-transition metal complexes ; amino acids

Sažetak
Ferrocene derived phosphine ligands have been extensively studied in catalysis with emphasis on asymmetric synthesis. They represent a convenient blend of the high catalytic activities of metal complexes bearing phosphine ligands and structural diversity owing to the properties and commercial availability of different ferrocene scaffolds. For several years, we have been studying the catalytic performances of phosphine-transition metal complexes with distant chiral information source incorporating simple building-blocks such as chiral amino acids or amines. Herein, we discuss the synthesis and characterization of novel chiral ferrocene derived phosphine ligands, and evaluation of their rhodium complexes in catalytic enantioselective hydrogenation reaction. Preliminary results showed a promising selectivity in catalysis (e.g. 87 % ee, up to now).

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA