Naslov
Ionic Hydrogenation of Organosulfur Compounds

Autori
Eckert-Maksić, Mirjana ; Margetić, Davor

Izvornik
Energy & Fuels (0887-0624) 5 (1991), 2; 327-332

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Ground-states; MNDO; Molecules; hydrogenation

Sažetak
Ionic hydrogenation of the three most abundant types of organosulfur constituents of coal, aromatic sulfides, aromatic disulfides, and benzo[b]thiophene derivatives, in BF3.H2O-Et3SiH is studied. Reduction of aromatic sulfides results in partial saturation of the aromatic moiety and cleavage of the corresponding SR group. Aromatic disulfides undergo quantitative sulfur-sulfur bond cleavage, while benzo[b]thiophene derivatives produce 2, 3-dihydrobenzo[b]thiophenes in high yields

Izvorni jezik
Engleski

POVEZANOST RADA