Pregled bibliografske jedinice broj: 81601
Building BLOCK strategies for the synthesis of molecular clefts with inside functionality
Building BLOCK strategies for the synthesis of molecular clefts with inside functionality // ORGANIC LETTERS, 1 (1999), 2; 199-202 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 81601 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Building BLOCK strategies for the synthesis of molecular clefts with inside functionality
Autori
Warrener, Ronald, N. ; Margetić, Davor ; Amarasekara, Ananda, S. ; Butler, Douglas, N. ; Mahadevan, Indu, B. ; Russell, Richard, A.
Izvornik
ORGANIC LETTERS (1523-7060) 1
(1999), 2;
199-202
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
UNITS; CHEMISTRY; DESIGN
Sažetak
A new general route to U-type cavity structures (molecular clefts) with inside functionality has been developed using wall extension or base/ roof assembly methods which draw upon (i) the 1,3 dipolar cycloaddition reaction between alkenes and cyclobutene epoxides (ACE coupling) or (ii) the Diels-Alder reaction of alkenes with fused dihydropyridazines (s-tetrazine coupling). In this way, functional units (e.g., crown ethers, redox active naphthalenes) have been attached stereospecifically to short-walled bis-alkenes 1-5 to produce cavity structure 6-10 with top of-wall separations (C to C) from 4.5 to 12.7 Angstrom.
Izvorni jezik
Engleski
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
