%PDF-1.4 % 1 0 obj << /Title (Impact of Mixing Parameters on Homogenization of Borax Solution and Nucleation Rate in Dual Radial Impeller Crystallizer) /Author (A. Kauni, M. osi, N. Kuzmani) /Creator (WASET Zend Publishing System) /ModDate (D:20160705130259+02'00') /Subject (Interaction between mixing and crystallization is often
\r\nignored despite the fact that it affects almost every aspect of the
\r\noperation including nucleation, growth, and maintenance of the
\r\ncrystal slurry. This is especially pronounced in multiple impeller
\r\nsystems where flow complexity is increased. By choosing proper
\r\nmixing parameters, what closely depends on the knowledge of the
\r\nhydrodynamics in a mixing vessel, the process of batch cooling
\r\ncrystallization may considerably be improved. The values that render
\r\nuseful information when making this choice are mixing time and
\r\npower consumption. The predominant motivation for this work was
\r\nto investigate the extent to which radial dual impeller configuration
\r\ninfluences mixing time, power consumption and consequently the
\r\nvalues of metastable zone width and nucleation rate. In this research,
\r\ncrystallization of borax was conducted in a 15 dm3 baffled batch
\r\ncooling crystallizer with an aspect ratio \(H/T\) of 1.3. Mixing was
\r\nperformed using two straight blade turbines \(4-SBT\) mounted on the
\r\nsame shaft that generated radial fluid flow. Experiments were
\r\nconducted at different values of N/NJS ratio \(impeller speed/
\r\nminimum impeller speed for complete suspension\), D/T ratio
\r\n\(impeller diameter/crystallizer diameter\), c/D ratio \(lower impeller
\r\noff-bottom clearance/impeller diameter\), and s/D ratio \(spacing
\r\nbetween impellers/impeller diameter\). Mother liquor was saturated at
\r\n30°C and was cooled at the rate of 6°C/h. Its concentration was
\r\nmonitored in line by Na-ion selective electrode. From the values of
\r\nsupersaturation that was monitored continuously over process time, it
\r\nwas possible to determine the metastable zone width and
\r\nsubsequently the nucleation rate using the Mersmann’s nucleation
\r\ncriterion. For all applied dual impeller configurations, the mixing
\r\ntime was determined by potentiometric method using a pulse
\r\ntechnique, while the power consumption was determined using a
\r\ntorque meter produced by Himmelstein & Co. Results obtained in
\r\nthis investigation show that dual impeller configuration significantly
\r\ninfluences the values of mixing time, power consumption as well as
\r\nthe metastable zone width and nucleation rate. A special attention
\r\nshould be addressed to the impeller spacing considering the flow
\r\ninteraction that could be more or less pronounced depending on the
\r\nspacing value.) /Keywords (Dual impeller crystallizer, mixing time, power\r\nconsumption, metastable zone width, nucleation rate.) /Producer (Acrobat Distiller 9.5.2 \(Windows\)) /CreationDate (D:20160105114001+02'00') /PXCViewerInfo (PDF-XChange Viewer;2.5.213.1;Nov 8 2013;19:55:11;D:20160705130259+02'00') >> endobj 2 0 obj << /Type /Catalog /Names 3 0 R /Pages 4 0 R /Metadata 5 0 R /PageLabels 6 0 R >> endobj 3 0 obj << /Dests 7 0 R >> endobj 4 0 obj << /Kids [8 0 R 9 0 R 10 0 R 11 0 R 12 0 R 13 0 R] /Type /Pages /Count 6 >> endobj 5 0 obj << /Type /Metadata /Length 6712 /Subtype /XML >> stream WASET Zend Publishing System 2016-07-05T13:02:59+02:00 2016-01-05T11:40:01+02:00 application/pdf Impact of Mixing Parameters on Homogenization of Borax Solution and Nucleation Rate in Dual Radial Impeller Crystallizer merve Interaction between mixing and crystallization is often<br /> ignored despite the fact that it affects almost every aspect of the<br /> operation including nucleation, growth, and maintenance of the<br /> crystal slurry. This is especially pronounced in multiple impeller<br /> systems where flow complexity is increased. By choosing proper<br /> mixing parameters, what closely depends on the knowledge of the<br /> hydrodynamics in a mixing vessel, the process of batch cooling<br /> crystallization may considerably be improved. The values that render<br /> useful information when making this choice are mixing time and<br /> power consumption. The predominant motivation for this work was<br /> to investigate the extent to which radial dual impeller configuration<br /> influences mixing time, power consumption and consequently the<br /> values of metastable zone width and nucleation rate. In this research,<br /> crystallization of borax was conducted in a 15 dm3 baffled batch<br /> cooling crystallizer with an aspect ratio (H/T) of 1.3. Mixing was<br /> performed using two straight blade turbines (4-SBT) mounted on the<br /> same shaft that generated radial fluid flow. Experiments were<br /> conducted at different values of N/NJS ratio (impeller speed/<br /> minimum impeller speed for complete suspension), D/T ratio<br /> (impeller diameter/crystallizer diameter), c/D ratio (lower impeller<br /> off-bottom clearance/impeller diameter), and s/D ratio (spacing<br /> between impellers/impeller diameter). Mother liquor was saturated at<br /> 30&deg;C and was cooled at the rate of 6&deg;C/h. Its concentration was<br /> monitored in line by Na-ion selective electrode. From the values of<br /> supersaturation that was monitored continuously over process time, it<br /> was possible to determine the metastable zone width and<br /> subsequently the nucleation rate using the Mersmann&rsquo;s nucleation<br /> criterion. For all applied dual impeller configurations, the mixing<br /> time was determined by potentiometric method using a pulse<br /> technique, while the power consumption was determined using a<br /> torque meter produced by Himmelstein &amp; Co. Results obtained in<br /> this investigation show that dual impeller configuration significantly<br /> influences the values of mixing time, power consumption as well as<br /> the metastable zone width and nucleation rate. A special attention<br /> should be addressed to the impeller spacing considering the flow<br /> interaction that could be more or less pronounced depending on the<br /> spacing value. 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  3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?zrzc+ sA'sjmi'vֶ\'F3`vRmTRssݕ:&A"Oe <W g撐Q9;zMS##0惈"_i s3Sѝ?7= ?MnދqޒgܡmLh΃ӛpn3?g84f:#(|>(?zF`à G_Q;(n+@:aIIHgO h73;_VdW/27 1nɻpe-o :r@z7Im,~uun2'AKk-;[0T-V3:b]g\`kܫVי3 'j!O?ggAqi 4Whw*X"ѿ|?Qa3,pm5`Ɯp0rnʨ]uq+y8@qAh&՛m :-v2mncs\8 U:(/%9 ,8M8@4 ` hbUE9Xw.C=-ΏJ~Aht·Pl[{s߹Oesvmdu{ݫx;DwrHv @ w=Ψ0?ŷ# DsL\1G.)tm#Uwo[S+cVeNճ?sYINczExucZCF6[v}[li0IV1q[^b h&$TS}X~cOq#rm}<} sew7+OFx3*t>58-ԒR4lƫ=X~--hu(Il4?d=U~ u i*'P W*},]-o:\u'}ܫ8x5_^8cGT;MSa>!՝Qҿ6)QVkYznh{-+kkMxޱs5thԔau]mTcoG/eE7#{i}u햟lqD*ϥO`u]mTè_I}cMKYCD_fz78[/eѶ?Q2[ }'1V/kl 0;.7M[`q3 )fW=ABn~\$réU_hk[a.q;X6jt X.ҫt7S$=ӧ<$7#' Q\ns`Z~OӦA<9K![5UVSGLZJsr[0xbۖEHq%Vƻ}`p[UPW2;[ԀiwE?F? _i)zF u7{>^MYa ۻM^➁ӯm74,6WCܺjL_5ۇI u*ٍc/=^X :ʝpۺQ>eWfۉ|f/fTt1T\4h_i)q]VN6C*^ lg3!̢܎eV`m۱k$hmŦQs$e31{*mLX鰀=l )ƺsoTގkbI$l-=|G /ڧFﳏ|FRI) endstream endobj 129 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 102 /Length 2726 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;fo"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ? oQF~R~Wx(~?;))O߅_MV?2:~" +?y z9RVLzggSa3?Q=ֺXiL?g%/ -L5%ga`R)[dǒzv6a>3%`#~))n3qE6l9F" {+W]]Gҩc (tpqɡͷP_=GrJm];(V/AF*# o8?RRlnz7]U:'پwJ7(RSFzka5߼_MUG'Mo¯IM&u,3{βG]g .|zmm;{cc@|䕑ʋߓW>/{.x}ype]eY }%Կsh+!s hc\Tx0IZ']b,}ѩk\#b]}#lK#t: ))4ߋfa0׏ 7W![ Z'bG?"mRS k?3j9z E߾%k@oQܒ1>ێwg?PK8E߾|cVe%'Whw*?T⊁`!䚞<I))O߅_MS~Iah kpcU; {X/itW} e#7d{ʬikA%40ݕvux]Tljj'kcI%mmʛkhĬ:v- þ}s/]eYtc}$:IvIM|_M]ah'h04_ڽ;3HN})DsY]Ot5װ8VA0AcztHgޒtm#Uwo[0:0k`p` #`u6zISnճ?sYA`/fֶ3pi=vlwN蒝TI%)$}JOOp#v0$nX*/hF3䃕ʽfeq JlI)I$JRI$I$$I)K c׀w8 L^ؕQz Iz{ f|S=uvsN=m;OmJ%2w8]VޅmYol-I%)$IJI$RI$sCIw1b[QU2j@i7GګW0{hhsNAޛf;&MmGݬfF%= K%j+ʬb]fT$Y #U>eOrhk}|GͶN餲}IAՋ躡^i.)TCśI.cb 45piiB[l1;k.zwHc[ߏs3 y{ie,̿X\lݰ~D.h0H&,.ǧ]?[?Cscz[:F+sp{_kG4<|ܒJ~ƞ11n2?J ;Fm Ì w?%I)VV!pϲ m<|@v z+q?gNk>$ k[za˹6Catz[~[c $ endstream endobj 130 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 118 /Length 1585 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;vo"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ???o8Xcۍw츿k4r_eC_SKq>]./ܗqh},1z_?W~ˋG%\_5?%4@ qޗan7߲} IM/?o8Xcۍw츿k4r_eC_SKq>]./ܗqh},1z_?W~ˋG%\_5?%%I$RI$I%)$IJI$RI$I%)$IJI$RI$I%)$IJI$RI$2krmeϱt)UuW0YKen!ILol-sN;T|V;/$s]|7>֬ηs3t(.>vYUڼ#k BxqƇ< :{N⽌h,v^ىVf-9uk]m8n Ȱ]ksc'zUExT7"U<7]/t$(RI$I$$I)gT?ZzKCJ*7u[6=]C\`:[eP>C.ůSW>}UW(}=268I#oe#ƿ/::tcяX6 hIVdl%I$HRI$I$$I)I$JRI$I$$I)I$JRI$I$$I)I.K}ne_b>UpIod>'_W>ft΍C˸ý_ma $W@6$ RI$I$$I)I$JRI$;YYuxb`/˱չֺ8 s9CHi6ov6Eod8c9 OC-/U$UI1sRKTSRKTSRKTSRKTSRKTS endstream endobj 131 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 118 /Length 1859 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;vo"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?nұrshƭ9;"$_Hƻ"XqѶ4D8xD m|\|+r|Յ_+xq<,o R^ŐMn.0xD}B.?k԰z~6Z֓v{)e՗m> ])$I)I$JRI$I$$I)K;"gY,-iKZ*W}/UU=J]64# kPư2rz:skY.xǙ | #u 6x@=FKmIJ4DGhVpq)oE &R6mAӮV:їS[KImsa_I$I%)$IJI$RI$I%97>'zrII%)$IJI$RI$I%)$IJI$RI$I%)$IJI$RI$\Y_ wA/ˁ+a-dS9p?e5., INYz}CTSt ~'EI)貿_W]Z$'rk \Y_ wAk$ˁ+a%9p?e5Jr., EI)I$JRcǏt@0$ )=Dua[YmNiyt9,9_p㫜[E[}kKUI$$I)I$JRI$ŧ5vz;\oIi.6h{0SQߏf8ɥ◖c^opФm%Rȷ?mvun64sx>֬T?3-"݂7sx$}%՝f-x5mykc`|m̳2 {Ylt餱Iпw]Vn D!܂y^߳[Ů8G9O%:.u-c}JYx^GsO_]JRI$I$}] n6c67^[o-tJM]u[eT@wu~]6 $'|FYە}ZCM Ջ_f#p2ko[k˝Y̳dmq?%I)oMu=~ G-ftƶf|Y0=%|J~ v -آ;gkޯ<_:ݛޥ[,-w Cf#A DS6F7C}O]3Xjqoځu>~+_*_*_* endstream endobj 132 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 102 /Length 3378 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;fo"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?ڝ7U{/ڽ3O֩׏{R9L586ﴜ:`4}8'cJ'%;ê]'i|*'][01>k;R|տ3,+ڒ:oʫz_:oʫz¿mޢr7_IMڝ7U{!za02'XUO3,+§~/N3+qpq(-lDiU_U?q5u*kkKԚZ=|{s:iREyL]c*jȟ;r-k<*owd_oF"f>LooWhq"49qׅvs*.c[[d`qCuxŸ` ۿyIK)|=6id4#>a_bGV,ck4mMoOQVkw~bى)ylc<˝c*`3l2紴[cGl`}NgSbKWgX1csw~`7>).lakc͕0koF6M"к;! un=QȀko{x<%/r9c}wDX8e;dulu6eǷx$FwQ4 .Ψ+ǎN|[oi嵃ݫb_]ۃl7X.)"~X`m޼[ԫN.}/˜CtoIm5~vm[:{(]'zoϮw]Bxo`t,+ ί1Es}}&HKUZr^5տ^vR|IM~m[oG_j?hڛ5b-ϯW6$ںOZ>4zp{]ZQIMt}LrNVgUͭ  i OWIKG՚Աw inӡZ.ߚ`HuZ#t-wwuVZ5k@  GTA؇+=!$uER?{j?_i}ve%2Akc.g/vUz[;Cҳ$ 8~QǜVJǗOїCgO]/m<[&߂Z'vl[vhӧTT鴀_MgIUӷj~kZlfp#Rv>u#~Χ%%ec{^zJk~Χ%%өK?RWWdQYcCZ5 O%#=>$p&?JX ͸Zl`81wp-V#Ul7OߒZ(BAݩ?RbY6W{tYp@Vq1܇ҿrr 5nwШrL7v9:$W[H hI pOJDzrm@kvvspS}ԸO Iۧ1)qR/`zo&8;]1ܬ>%!ǫr6^?1ܮ!cG%#ncUcQ21뱿䵇 GWόIL~ÅR>Tz!ZTh6tW?WAGM))OUΟ=Oӏ, ӹiGp#VJupr\V@.6[#G.:Ɔ@<ͦ^z?y'lλV'J鵷mÒ%ĝ,x쒭l/INq_9=FOo$eD6 _; W :SꅛqwACzG;)*]_ף>1Wn ߇:?;au<gRSz@wZ?mY*YmXs'q>l;F L iso^[A5l'o1J_+' UMh6Z,s9-k[I'8&6ݟ):u|J~=8b '}(H}<_r_8$/G7,^JOM+Oz$̮[ sGY98'T]WԣO{|_?1ox=⸴ ~H:74Gǻ ؿǥqn/᷇m|t_<$ endstream endobj 133 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 102 /Length 3401 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;fo"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?*+mqC :^+ ?n~~W&AMUgGtLїN~8܇b׿mwh['cI`|:X`&ٶEa6=>?骴י?F@o/;H'bG.S{=䆟.sA $s ;י13Z-YVK[EotH'nET8N tebf`{K˷Z7!Oӝ[nPV mC/{,(pMzkB3Ik i-{'Z +e{+h!hb0LkӲ οKe = gfg&^g3>|?cC#K#oa>>ٗ2G?F-%7?WAGM)e?d]3 bվƺhi ;yFRSOV]U)8i)J?-ϯVmkuh$I]ԪX9р\- hԒmpyQ}nFX5k$n )j m>)):AnxTϸꇭy-#|Xʧ2~i$?v )7\n}?7S}f;UN=eqq3r73UȤzs|̱`N= ΓJpŵ̺{]jk-yx{w!FӍcG=іN]kup.` l#wj=tϟ+nW[/}%86FWJՁ,p.#sjcQUbr59ϯ$8n86uX=Fac`h׹V7?M%CA8o"vɓSmǪC{? 'mQ4??lI%?JԾ6-H{Qs SwTLj?//IOQs $Mc? aI%?N]gYmsU4Xc`VvUklw˜}O> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;fo"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?'|J~?Zv##S*am5gĔ_ЇexG C?#տ?P?71p Ɠ@mpxy7 ?>HcFΪ4|6Mvde!h4RSb{ h! k~۠>&7zgg~><Sppdu^f0L=bJnޯwE&`#О?11ūeMn-kr6RSqK hy}VM?u߹UO%!y9o#5-Ԇl-qk h4/e8 /ԺCZ5sT {:ٛyngKogWZ[[ +'أdюKpwŌ!$F8ۍeZjvEkŎôsDU~F38sKRS[a-sNh RѼ {VO~k(XCX) :lז1WG}C: \I#0%7WAGM*??ioٳЍӤFkë4Qa{G INI(n"ZdH$]xo%kɷlzMcN?wE%&I$RI$I%)$IJI%}:_cIͳ1,hvM1'OlZq}b]`KJsr)7J¢qoȪr]&^>kzz1\浆8ܫt|[~uu z촂[X3@O%]IJI$RI$I%)$IJ\VcA| cww0O#cuN<],mMXpx%7I$I%)$IJI$RI$I%)$IJI|J~I|J~I|J~I|J~I|J~I|J~I|J endstream endobj 135 0 obj << /Type /XObject /Width 84 /Filter [/DCTDecode] /Height 118 /Length 2310 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;vT"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?V}`v=?q6I=Z >>;:&CS꠆bINw ̜Z.n:H쯝}4%TXu[{6P5F"Kk]nf<7'cu{13''c=3Qk0]qE.լ 3}yY8p$:c0Q:n?Y;=k/}!@S=6ΡF=U4DڞZ#%5sz_s [;'{߽gN[qC ̢}Y a~-cc"-XxS=m?"JgS\ʘא\ր8I%)$INO֟ #-eB_Y%)$IJI$RI$mm{^aa|yY2ne^a޳?dz}bŌ,${?Pє0]cȮzěm!;>_wc}N~|NO6I%4>Y֫>k,?GϬZ)I(Ymu7} h0? C :R(867uĨ68; ⒒$h&a"+pVR V VZ7{B 5i[[maYSmTcE淾;6COmRS"4I Է~7D7D/ I%8[o#YS$Y?۬|WB~Y֫>k$+SC2ظިɬ6l~S㽭k1,!en;@di[ӓY0hIN {Xll[ԼUdG]`TwKFQ^SlsEՃNUum!;4nƉ~55> AFA> )pc-k}5#JR3&U۬܌=7m%uk7?tKrfqlUqh;A>));wџl퍓$I۽<픒SB_Ydi?W}bIJI$RI$I%#ȧ]{+lnqI Ǚr6ߒ?ƍyzSpuO􄶚kG+νS=[_2qKtSz?}?Kg6=qo_iGI%9Z,UXO֟ #-dl0XY.}SSusvǖ%2IRffn+64pimuna<'tx$U%Eˠ9㾖!IU[_YdnG֦7O)x6ͤas}G3? #8fe_͸TɥCk'mg;|'7|>c7$20./ZS W] !dZŬno}3*ʍظkZ⟢tSI1{KUpc]Jq[}GuuMuZGMt-ʯO[ЛmNEnA:P(k[:DRI$!q ǿ&5Xe5;7@]jۺ>OD:nm9µ )ޚeNzoݟGԟ)Cgǡc[ $֟ #-eI)%I)%I)%I)euk1zcm+̆NCC_iI%?R_ds;)/IO endstream endobj 136 0 obj << /Type /XObject /Width 84 /Filter [/DCTDecode] /Height 118 /Length 1690 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;vT"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?Y֫>k,?GϬZ)I$JRI$I$.S3:^}f2_]NsG4ĞWO}̢Q[!\ehѳ⹮}ybg_HyCYei zV_0a%=oz흿J<Cۏ/l?mSSOj羶;0.pycE Gö IM^vm8~Lւl ~kf}%w0?в7%%W/ų*Z~H# 5ͦםc] 7wxd6RS:z]qүfw56|~r~S4(2HhkA:mc>bV %g+!zV3곂kʽɆߴFUb4zM?HYO-IKGzF 8ÞʰB֑֞ خo>,m987 [K]ϓ$oOӾRB߉ۧ_SjI)B_Ydi?W}bIJI$RI$I% 9'OL\Hg:-}eSүh?IX*3-V2pm\vX6GsJz}zޟe$GG/7N͑ $֟ #-eB_Y%)$IJI$RI$'!ԺkbZ\LhcX?+ene/4Uv.Ene:ǷiYŠcbӎ^)ckv%%%I$RI$I%)$IJI$RI$I%)$IJI$RI$I%)%I)%I)%I)%I)%I)%I) endstream endobj 137 0 obj << /Type /XObject /Width 4 /Filter [/FlateDecode] /Height 2495 /Length 29 /Subtype /Image /ImageMask true /BitsPerComponent 1 >> stream h  mn@pd # endstream endobj 138 0 obj [/Indexed 71 0 R 99 238 0 R] endobj 139 0 obj [/Indexed 71 0 R 239 239 0 R] endobj 140 0 obj [/Indexed 71 0 R 200 240 0 R] endobj 141 0 obj [/Indexed 71 0 R 225 241 0 R] endobj 142 0 obj [/Indexed 71 0 R 199 242 0 R] endobj 143 0 obj [/Indexed 71 0 R 251 243 0 R] endobj 144 0 obj [/Indexed 71 0 R 164 244 0 R] endobj 145 0 obj [/Indexed 71 0 R 78 245 0 R] endobj 146 0 obj [/Indexed 71 0 R 239 246 0 R] endobj 147 0 obj [/Indexed 71 0 R 99 247 0 R] endobj 148 0 obj [/Indexed 71 0 R 188 248 0 R] endobj 149 0 obj [/Indexed 71 0 R 205 249 0 R] endobj 150 0 obj << /Type /Font /Subtype /Type0 /BaseFont /NJIEGJ+TimesNewRomanPS-ItalicMT /Encoding /Identity-H /ToUnicode 250 0 R /DescendantFonts [251 0 R] >> endobj 151 0 obj << /Type /XObject /Width 74 /Filter [/DCTDecode] /Height 126 /Length 2226 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;~J"? 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  3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?TI%)$IJI$RI$I%)$<ޠ1o` y WF?ta,\v[D<5UZr^OQ̬YƸbOwr.'Os-9yo8F[OT䫩#J(:J>I$%$I)I$4:-YYXyؙX9ս@II.c}s]ȽڜWN\jIS+0;#(z]٣̠C }1 L3֢8<$qh%3vvNy5tm %bybb^̙}<{-hh h #ܿ/%K&0xs'_]{t;vsNy 􌞯E Yeմ&Ďy?aaci{2~ԯ}ڙ>k_Kgwzoo$I)I$JR񛛇7`;7ۗ.qԟ:I" $ORcZ`!I$P='鵖ncu&;"}V_/kf Tu;]?c!և:j 'UpU`Cm#️$IJI$RI$I%)$IJI$RI$O잱y?KOX˼gI$Y%'G?#I)Idwl$dqJuY?z]8I/=c.?$d,l2fF;Ŵ%nw잯y?@0qk9 i&y5yu%'G?#I)Idwl$dqJuI$I%)$IJI$RYX2P[6[Eo>qS.2Cn] =zšxn5% 8=/j :Ca C*Fߦj5Cbb<%s7fĉIMξZsoe>/`;l1X܇7W}Oq[뱭$Jlzᡔ_ E5[*d^3葳%"Dnf,/Yl<^u ~݉Gزr iC̮\B}V߹ȯ%FWesrͼZu zO[F~D8^xgu/`k_^۪sk7V@{#5tf.}Ce>vj|ԫR_iQ5]%6~h;C'?kdx,,q=|οrJ endstream endobj 157 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 100 /Length 1868 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;do"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?T'~(~('~(~('~(~('~(~('~(~('~(~('~(~(;~bU?:]kiȦ,;nzwS>M?ey`sRSu$IJI$RI$I%)$IJI$S~#_csv6K:Lsϸ MjQ.?՜Ӑ~OWdֻuT!ins>?}kSu(mTX1M4 ~\tk3>6d:VGǂJ{DI%)$IJI$RI$I%)$IN.w2]MZg׸ÚOhӱ6(pd}9URI$I%)$IJI$RI$I%>=GUvkHƦ6:Þς~}z^=Pji%i=<CcYseqߐ|B]z4U~`$jVum%ii!|wK>[^EkIԓ%z'}-?l.;^L87njLDRYɿD[8^?ߏwjI%IOI/RIOI/RIOI/RIOH9e%l_M޾ݻi$ZN7G֍>]'Uo~vn=hݺ=cM$P~?6xH} endstream endobj 158 0 obj << /Type /XObject /Width 111 /Filter [/FlateDecode] /Height 100 /Length 323 /Subtype /Image /ColorSpace 185 0 R /BitsPerComponent 8 >> stream hW7Q32bF0"dGOB D'!{-ocڝs.g_ iYL7&#)(r ̅bRb-qۉ6#oNrY55rOw:4"7حDCNS@PWC៚&ƘqD OE݅&EԦbѬ}K+D[[ ?{|sGD's؅|s[YKc> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;do"? 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[C"XYu;F?62zXvLWIT֍(6dWoGM}&NXGcuʒ$IJX_h[ Vb )I$RI$I%)$IO9s,YΫ/5ͤc2v1%kVs)67+">lYמ~:Necwsw/Ax 5[l}Ťm1s^ߑINI$$'@3߭Ƨvcx-5ik-pGMZ8c 0.*`dŴIO@:oΞvUQ{\ihk +]duwGhl=e{ h%7qЩe_H# 1>t&B2?:vۜ\Z8$> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;~o"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?TI%)c_!}l,{Y/ϴ$a$IJI$RI$I%<֌̧>Ewdn (3+2ΓoP%5W[Y>rKi9*=ca1z6~VZǶ+Z];i\=Ooּlr bTcMlϵVns klKp:2z 5nKX^e`B#+'o\{,jhQK8IKI)gtkv[[ wag? >۬~Sgmx&E`]dN4 Xhg`Shs 誫7:]CdNɺ& :KpE6=%ޘoXa~SI$,{Y/ϴ-w+1&-kp5$'$kA$ ;I$I%Х'G5une̩԰={c{$QRؖmuYXYP1ڏ䫫rri}6E`y~j]K걡xA k3-Wv6H-zcO-;~pRI$I%98_VzVlklֵ̋Xy{jQӱmͬ==nsZI%)$GP}.9ϢZZ^U4'⒝tWܼm>uԇS\ }^M98J*%8_H|zp v%=bֺ$NJRI$I$$I)I$JRɺΫ#pF6AZI%4uc|[luMkP^才(>~Eš6;CZ>e$I%)$IJI$RI$I%)$IJI$RI$I%)$IJI$RI$ endstream endobj 167 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 100 /Length 1831 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;do"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?T'~(~('~(~('~(Ұqo|<=v Vc7ln9݂Jz%?'\VbZ$4xZ+']VoUKmcV\8Ju+qumq 1auW2qN^Ew]=:q+K.߻|97+)Sd9| U0k}hꖚڝXZC\))g[ۃօmhs z^1pmsc%#\v[>eXmgdt%}m q1 6l$I)I$JRůW麯jX7UINI$I$$I)I$JRI$I$,Ze֭_,u_Ԕ$I)I$JRI$I$'ZYfc(w)m{Nu܎ҽ^GPv| x ӓux;ӱWYc/_ȭַK6Bغ5$DI$Z_,u_կmS[sCZ++'~Ce>][>RSK+FF^';KeڴLCINJja:I.5}kޯݎz8hsY8m\SJz4qs Wi}9ٺxZ,יִS\jƳ=OT8HwIN(_-l ޹w򾲱xFcUwpt2nʴcV I.tޝM޽8qןpJRI$]MWcmǀ ~K1(ͩZ$4,Ze֤iegQ_Uu.p Q$}TcW\Y^ӣdVnwWv{ߓF3Ͷ=WNkI%0`%stkF[~,1^5MĴM9 a$2~E.5ݣ~;Ė𺭣n IJI$RI$_,u_մkŕn?ZI%)$IJI$RI$ʩ$ꤗʩ$ꥋ_,u_zI)%I)%I)%I)%I) endstream endobj 168 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 100 /Length 1861 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;do"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?ߪaxuqn h+[NqFgN8%%+z_Q}wY:Xm﮼ُY1;cNWOzD5I=JtY}k k{]CXZO4kj7U}M-su$kY_ib+W~%;I$e::xzfyh*}37SeSu4vmwpzuϿpAԔIPꞟQc.}NsK5N04@mUtmc}w׬e{,{RS.{dt?4ûD-46OWd㳤2jfQ.u>X]M\}W8]^̼ʥF8#]Pko`i)x%a-F'I%!ˡP_ =mI fUveߚ]K K[FѱtY_)\|L~Ҳ7cMӞòʭ TШ[MW3em<8}%8=m&(pslF挾 Z455@&-k.$p'tvM2x\a{$/Zޗu59U5]k[VMscA׀#i)I$Js_wXoR.||I$$I)KY_ib+W~%;I$JRI$I$$I)I$JRI$kŕn?Z-MRSI$$I)I$@S1{39))P32-%qUcGY}OuA ?t:nK'>C,Z-Ocڋ4>U02z;YEݓc{c >`;Te6;{\AW4k5>o滒9Z)$I$$I)KY_ib+W~%;I$JRI$I$$I)I/RIOI/RIOKY_SRKTSRKTSRKTSRKTS endstream endobj 169 0 obj << /Type /XObject /Width 111 /Filter [/FlateDecode] /Height 100 /Length 543 /Subtype /Image /ColorSpace 187 0 R /BitsPerComponent 8 >> stream hb` 0213Z7jݨu֍Z7jݨuQl +c⦛u<|BNXDAL>HII)iX'#fTTR&:V M- Kuz}C#T&r LHΜh`a&}=ttru.n@ÓNŚ?lc  u Q `Q@Cpij]JjC[&XyE4ue4TSuu Mt[Zi][{=좧u=4DwhjI&N1sl9c6 57a|nmQ0 F(@\Ӷ!obZ[d)ò+VZfhBQi-[cmv1{| ۻo?:`qZ;|~``k``9Hc֞f8y4Cݙ\uZ/ 1l|*õsGKQ0 F(`/O endstream endobj 170 0 obj << /Type /XObject /Width 26 /Filter [/DCTDecode] /Height 299 /Length 2168 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;+"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?FE,בkX?5o']$q$RI$:QcOI93GX4IqV9zHSy4x+[r(uwJdGV8q>c55x+!ԛY q.! 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H[X[Y;= 8PTH:!,99  WtqV7wr7ƚ&:*[Zc][{tSw}]&N[>> stream hұ JNzQ+2#cqWh'M endstream endobj 176 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 98 /Length 2140 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;bo"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?TI%)$IJI$RI$I%)$IJI$RI$I%)$IJI$RI$uNѬn _m*C?aۛkiƥ{2|S瘝9V2,.7YP3J]{+ z_S$_GDé{ ~k]mpLnײMv7K]vs^ܝ/IVu:܁slxP[΁ü˼S 5 OS3 B O-'QKI$TI$$I)I$JRI,Uv\F5;BWBxѻmS[%qNgvFΚNj[h!sxr^-wzZd_PfiH'ʧO.'b4!٣^mmڞx@By7Ck.NqCĺdaUV=Zs]R^gRuTSicHvwUߩ SsKG^wkS~++-g5̭V&vnHi;0ˊdf]u{I&sZ\I ]%Ϯ]_uKvCccXqJ\:7]7?#4[w$IRXǤodq@DY40D꩙0e/BhU,wUi}7b0q3*oãszF+lwv?W|Oޖ^F,K___z=W 78.7L.`tXkOw~ר^iUqNUU,[Z N!dyg1ݏM}?t9)V˟.ۿ<>UkF۔ݶcK3SL&D,g܎q21$0_S>u>ߗKٗ0m8}Mo;]L0Ḵd8#{%JXQᤵ +?Xϸ 氽ZgIꖲ3zyn;[P: Lt}8S(_<oK/x~=ڝd7qk~Ν:sqsjvh!yZ^zL4ϫ} hIJ<~Ak =!7.^ML0@-\>q 2'!c8l47?%of͘ӫw5VgIӹ}Oo$.|夑db!b:GY<$8L?617 27e8}||Gܮ"dNI$ RI$nORC cQs~-V䤒JRUs,ikIN>V^>+lm{A݇e<=_ё:d$WzPǴ1|%dF\[[BZn#%6I$I%)$IJI$RI$ʩ$%eѰSo<> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;bo"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?TI%,@:$I$$I)I$JRI$I$$I)I$JRI$I$$I)I$JRI$gRuO`v'TMoC]3 6dTYS!8(?Ev7215@IN):?iλ?&IN):?iλ?&IN):?iλ?&IN):?iλ?&IOs~17[6:NlI%)3 @I'@N=pkeWsjul))أ'!XЖ9e^=d}k>KI뙮mvtZ8.ek$y8Ym/v%n#*MC1챍ARUnSs:v6[+4`ZvI%)$IJI$R\PÓk)W^{5IFX_[ӁHa|źF^= SkK$ү1 ,Y^}]45DwJΕU]~Xz=ʺJY hkD4pNI)I$JRI$I$f.ul)+0I;B8*I$7gۓW1퍾s[{Rd)Y5Bf[b̲DNxX[,~rq(Ƽ 9'^-V5x{laֻz>WM/ޗisQ.yٲ+'k:X))lĮS{k_-l>1ꨜb/8CQ '#F6g`!P3qž֋,h:51\ɉMX՛^ܼk\]̱jJOw]>[[MO{-kvg%=W_eՐ?=fNg }#Qi(~2]K唒S endstream endobj 178 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 98 /Length 1638 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;bo"?   3!1AQa"q2B#$Rb34rC%Scs5&DTdE£t6UeuF'Vfv7GWgw5!1AQaq"2B#R3$brCScs4%&5DTdEU6teuFVfv'7GWgw ?T?3?/#J%3OL҉)Ia3b?_?ؼ(Ė?3?/#J%3OL҉)Ia3b?_?ؼ(Ė?3?/#J%3OL҉)Ia3b?_?ؼ(Ė?3?/#J%3OL҉)I$RI$I%)$IJI$RI$I%)$IJI$RI$B3 N0;洴IIR\6gWN- > p84z#a]0tI$I$$I)I$JRI$_=_7Df/UuWq]i&{4xꗞ쯳a07ݟh0}:5@z.%9Y-Wz$]N#0H!ֶ0L|_:߬tv1v5\ݫ[`GUn`e C;[u\{rq{^L%{HJ$dW"$De]RI$V$IJI$RI$Ui lNn{ hJ,c"#daT_cioӱ熴.Ww՜9p}jnn*8_mcQSEvSݗ+smX6b8.wt/LTG3r1o<ޢ :Nk6 q[68k/at>^NWC˞yJ'쎕Xq&UI6XKH%I$JRI$Jv}XU<aM,w H΀&12"1Jմ\v[u{xkGrc㹄^拚XPqRuNwUoӵ:yk> stream hb`YLV6vN.n^_@ƶ Bb4MJZFʔWuH**)@j괶MCSKӧeF&%mm0h.nP{x6/o_m~4-(8$ mQ1Pf\|B"m-KJNIM32hk[vNn^>]PXTL[JJ+ʪV[Wc76U7ֶֶv(2C&Nư 8pa#Gm'N:M7Μ=wlxt7mn߹K7SS9= Q0 F(`Q0 F(`Q0 F(`Q0 F7kM endstream endobj 180 0 obj << /Type /XObject /Width 111 /Filter [/DCTDecode] /Height 98 /Length 1798 /Subtype /Image /ColorSpace 71 0 R /BitsPerComponent 8 >> stream Adobed     $$''$$53335;;;;;;;;;;  %% ## ((%%((22022;;;;;;;;;;bo"? 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