Pregled bibliografske jedinice broj: 81089
Reactant adsorption in cyclic staircase voltammetry on spherical microelectrodes. Reversible redox reactions
Reactant adsorption in cyclic staircase voltammetry on spherical microelectrodes. Reversible redox reactions // Analytical and Bioanalytical Chemistry, 373 (2002), 781-786 (međunarodna recenzija, članak, znanstveni)
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Naslov
Reactant adsorption in cyclic staircase voltammetry on spherical microelectrodes. Reversible redox reactions
Autori
Lovrić, Milivoj
Izvornik
Analytical and Bioanalytical Chemistry (1618-2642) 373
(2002);
781-786
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
cyclic staircase voltammetry; adsorption; microelectrode
Sažetak
On spherical microelectrodes, cyclic staircase voltammograms of reversible redox reactions complicated by the reactant adsorption on lateral interactions in the monolayer. Attraction forces increase the separation between the main wave and post-peak, while the repulsion prevents the resolution of responses of the surface and volume reactions. The theoreticla relationships between the dimensionless responses and the dimensionless adsorption constant, the relative surface adsorption capacitvy, the Frumkin coefficient and the electrode spheriicity are given.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
