Naslov
Novel 1, 4-disubstituted adamantane stereoisomers: Synthesis and spectroscopic characterization
(Novel 1, 4-disubstituted adamantane stereoisomers: Synthesis and spectroscopic)

Autori
Šafar Cvitaš, Dunja ; Savin, Branka ; Mlinarić-Majerski, Kata

Izvornik
Croatica Chemica Acta (0011-1643) 77 (2004), 4; 619-625

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
Adamantane; 1; 4-disubstituted adamantane derivative; Syn-/anti-isomers

Sažetak
A series of new 1, 4-disubstituted adamantane derivatives [e.g., 1-chloro-4-(carbethoxymethylene)adamantane (3), 1-chloro-4-(carbethoxymethyl)adamantane (4), 1-chloro-4-(2-hydroxyethyl)adamantane (5), 1-chloro-4-(2-bromoethyl)adamantane (6), 1-bromo-4-(2-bromoethyl)adamantane (7), 1-hydroxy-4-(carbethoxymethylene)adamantane (8), 1-hydroxy-4-(carbethoxy methyl)adamantane (9), 1-acetoxy-4-(carbethoxymethyl)adamantane (10), 1-hydroxy-4-(2-hydroxyethyl)adamantane (11), 1-hydroxy-4-cyanoadamantane (12), 1-hydroxy-4-carboxyadamantane (13), and 1-hydroxy-4-carbmethoxyadamantane (14)] have been synthesized, and their respective syn- and anti-isomers have been separated and identified.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA