Naslov
Novel complexes of copper(II) with tridentate hydrazone ligands

Autori
Bjelopetrović, Alen ; Cindrić, Marina ; Vrdoljak, Višnja ; Pavlović, Gordana ;

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
Book of Abstracts / - , 2015

Skup
29th European Crystallographic Meeting

Mjesto i datum
Rovinj, Hrvatska, 23.08.2015. - 28.08.2015

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Hydrazones ; Tetranuclear and dinuclear copper(II) clusters ;

Sažetak
The design of polynuclear transition-metal clusters with novel magnetic properties is one of the few major goals in the field of material chemistry and condensed matter physics. Polynuclear copper(II) clusters, which exibit a large diversity of structural types are of particular interest from both structural and functional points of view. Tetranuclear, as well as dinuclear copper(II) clusters are of permanent interest in magnetostructural research, bioinorganic modeling, catalysis and electron transfer reactions. Hydrazones, which represent the most common type of tridentate ONO donors are often used as ligands in chemistry of polynuclear clusters. One of the most investigated hydrazones is salicylaldehyde benzoylhydrazone (H2SalHB). It is proven that H2SalHB posses mild bacteriostatic activity and inhibits DNA synthesis and cell growth. This effect is over 100 times stronger if H2SalHB is coordinated to metal center.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA