Pregled bibliografske jedinice broj: 779306
Dipolar Cycloaddition Reactions of Azomethine Ylides Generated by endocyclic-exocyclic 1, 3-dipole Rearrangement
Dipolar Cycloaddition Reactions of Azomethine Ylides Generated by endocyclic-exocyclic 1, 3-dipole Rearrangement // Journal of heterocyclic chemistry, 52 (2015), 5; 1447-1456 doi:10.1002/jhet.2167 (međunarodna recenzija, članak, znanstveni)
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Naslov
Dipolar Cycloaddition Reactions of Azomethine Ylides Generated by endocyclic-exocyclic 1, 3-dipole Rearrangement
Autori
Margetić, Davor ; Butler, Douglas N. ; Warrener, Ron N. ; Holland, Craig M.
Izvornik
Journal of heterocyclic chemistry (0022-152X) 52
(2015), 5;
1447-1456
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Cycloadditions; azomethine ylides; rearrangement
Sažetak
Dipolar cycloaddition of polycyclic azomethine ylides, in which the central nitrogen atom is part of a pyrrolidine ring and bears a methoxycarbonyl group with norbornenes has been shown to produce two main types of products featuring pyrrolizidine rings. In conjuction with results of quantum chemical calculations (B3LYP), mechanistic rationale was postulated. The key reaction step is unprecedented endocyclic to exocyclic azomethine ylide rearrangement by an intermolecular prototropic migration (formal [1, 3] H-shift).
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982933-3218 - Host-guest međudjelovanja u policikličkim sustavima (Margetić, Davor, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Profili:
Davor Margetić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
