Pregled bibliografske jedinice broj: 773179
Carbohydrate polymers as constituents of exopolymer substances in seawater, their complexing properties towards copper ions, surface and catalytic activity determined by electrochemical methods
Carbohydrate polymers as constituents of exopolymer substances in seawater, their complexing properties towards copper ions, surface and catalytic activity determined by electrochemical methods // Carbohydrate polymers, 135 (2016), 48-56 doi:10.1016/j.carbpol.2015.08.071 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 773179 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Carbohydrate polymers as constituents of exopolymer substances in seawater, their complexing properties towards copper ions, surface and catalytic activity determined by electrochemical methods
Autori
Plavšić, Marta ; Strmečki Kos, Sladjana
Izvornik
Carbohydrate polymers (0144-8617) 135
(2016);
48-56
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
natural polysaccharides; seawater; electroanalysis; exopolymers; copper ions; complexation; surface active substances
Sažetak
The goal of this study was to investigate to which extent polysaccharides (PS) contribute to the complexing capacity for copper ion (LT), to determine their property of surface activity and evaluate their capability to cause the catalytic hydrogen evolution wave (peak “H”) due to their adsorption and the catalytic groups in their structure. Complexing capacities and apparent stability constants (Kapp) were measured electrochemically for model polysaccharides (PS): carrageenans (κ-, ι- and λ-), chondroitin sulfate, dextran, dextran sulfate, Na-alginat and humic material. Cu- complexing capacities were determined for Na- alginate (log Kapp= 8.32) and chondroitin sulphate (log Kapp=8.14). PS adsorb on different surfaces due to their amphiphylic properties and on that way they could increase the interaction of copper ions with these surfaces by forming the surface complexes with Cu ions.
Izvorni jezik
Engleski
Znanstvena područja
Geologija
POVEZANOST RADA
Projekti:
HRZZ-IP-2013-11-8607 - Utjecaj okolišnog stresa na pojavnost i međudjelovanje biološki važnih organskih molekula i mikronutrijenata u morskom ekosustavu (AMBIOMERES) (Gašparović, Blaženka, HRZZ - 2013-11) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Profili:
Slađana Strmečki Kos
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE