Pregled bibliografske jedinice broj: 771867
Trapping Reactive Intermediates by Mechanochemistry : Elusive Aryl N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents
Trapping Reactive Intermediates by Mechanochemistry : Elusive Aryl N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents // Angewandte Chemie. International edition, 54 (2015), 29; 8440-8443 doi:10.1002/anie.201502026 (međunarodna recenzija, članak, znanstveni)
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Naslov
Trapping Reactive Intermediates by Mechanochemistry : Elusive Aryl N-Thiocarbamoylbenzotriazoles as Bench-Stable Reagents
Autori
Štrukil, Vjekoslav ; Gracin, Davor ; Magdysyuk, Oxana V. ; Dinnebier, Robert E. ; Friščić, Tomislav
Izvornik
Angewandte Chemie. International edition (1433-7851) 54
(2015), 29;
8440-8443
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
mechanochemistry; reactive intermediates; thiocarbamoylation; thiourea
Sažetak
Monitoring of mechanochemical thiocarbamoylation by in situ Raman spectroscopy revealed the formation of aryl N-thiocarbamoylbenzotriazoles, reactive intermediates deemed unisolable in solution. The first-time isolation and structural characterization of these elusive molecules demonstrates the ability of mechanochemistry to access otherwise unobtainable intermediates and offers a new range of masked isothiocyanate reagents.
Izvorni jezik
Engleski
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- Nature Index
