Pregled bibliografske jedinice broj: 74693
Effect of electron defficient bridges on geometry of double bond in syn-sesquinorbornene analogons
Effect of electron defficient bridges on geometry of double bond in syn-sesquinorbornene analogons // European symposium on organic reactivity : Programme and Abstracts / Eckert-Maksić, Mirjana, Glasovac, Zoran ; Zrinski Irena (ur.).
Zagreb, 2001. str. 127-127 (poster, međunarodna recenzija, sažetak, znanstveni)
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Naslov
Effect of electron defficient bridges on geometry of double bond in syn-sesquinorbornene analogons
Autori
Antol, Ivana ; Glasovac, Zoran ; Margetić, Davor ; Eckert-Maksić, Mirjana
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
European symposium on organic reactivity : Programme and Abstracts
/ Eckert-Maksić, Mirjana, Glasovac, Zoran ; Zrinski Irena - Zagreb, 2001, 127-127
Skup
European Symposium on Organic Reactivity
Mjesto i datum
Cavtat, Hrvatska, 01.09.2001. - 06.09.2001
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
dications; ab initio calculations; syn-sesquinorbornene
Sažetak
Results of MP2 and DFT calculations on dication 1 and its diboron analogon 2 are reported. Both structures show significant nonplanarity of the double bond in direction opposite to that found in syn-sesquinorbornene. The computed out-of-plane angles are 17.9° and 14.1°(MP2/6-31G*) in 1 and 2 respectively. Molecular and electronic structures will be discussed in detail.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
