Pregled bibliografske jedinice broj: 742997
Electronic structure of antibiotic erythromycin
Electronic structure of antibiotic erythromycin // Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 138 (2015), 550-552 doi:10.1016/j.saa.2014.11.076 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 742997 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Electronic structure of antibiotic erythromycin
Autori
Novak, Igor ; Kovač, Branka
Izvornik
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (1386-1425) 138
(2015);
550-552
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Photoelectron spectroscopy; Erythromycin
Sažetak
The electronic structure of erythromycin A(ERYMA) molecule has been studied by UV photoelectron spectroscopy and assigned (in the low ionization energy region only) by empirical arguments. The two orbitals with highest energy (lowest ionization energy) are localized on the nitrogen of the desosamine sugar functional group and on the ester group of macrolide (lactone) ring. We discuss how these orbital energies can help to rationalize the known mode of binding of ERYMA to their biological receptors.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982915-2945 - Spektroskopija, kemijska svojstva i reakcije biološki aktivnih molekula (Kovač, Branka, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
