ࡱ> !#0bjbjWW 4*==gnn<F++++<>>>>>>$'Jb9b++~++<<+b(0$v$bbvn w:FOTOKATALITI KE OKSIGENACIJE ORGANSKIH SUPSTRATA UPOTREBOM MANGAN(III) PORFIRINA PHOTOCATALYTIC OXYGENATION OF ORGANIC SUBSTRATES USING MANGANESE(III) PORPHYRINS Dragana Vuk1, Ivana `agud1, Irena `kori1 1Zavod za organsku kemiju, Fakultet kemijskog in~enjerstva i tehnologije, Maruliev trg 19, 10000 Zagreb iskoric@fkit.hr U danaanje vrijeme fotokemijske reakcije su dosta raairene u organskim i anorganskim sintezama. Pri tome su posebno zanimljive fotokataliti ke oksigenacije organskih spojeva, koje kombiniraju dobro poznati mehanizam metalokatalize i organokatalize s fotoinduciranim prijenosom elektrona. Zahvaljujui dobro poznatom mehanizmu reakcije, primjena fotokataliti ke oksigenacije proairena je na pripravljanje i studiranje struktura koje sadr~e karbobicikli ki sustav s raznim funkcionalnim skupinama. 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EMBED ChemDraw.Document.6.0  S obzirom na rezultate istra~ivanja provedenih na prethodnim istra~ivanjima, studije su proairene na sintezu 4 i 5-(2-vinilstiril)oksazola. Ovi spojevi, koji fotokemijskim putem daju nove policikli ke strukture, vrlo su interesantni za daljnju funkcionalizaciju, jer se molekula oksazola sama pojavljuje u velikom broju spojeva s visokom bioloakom aktivnosti [2]. [1] I. Kikaa, O. Horvath, I. `kori J. Molecular Structure 1034 (2012) 62-68. [2] V. S. C. Yeh Tetrahedron 60 (2004) 11995-12042. 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