Naslov
Potential role of silica and PCC nanofillers as compatibilizers in immiscible PLA/LDPE blends

Autori
Vrsaljko, Domagoj ; Macut, Dejan ; Kovačević, Vera

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
POLYCHAR 22 World Forum on Advanced Materials / - Stellenbosch, 2014

Skup
POLYCHAR 22 World Forum on Advanced Materials

Mjesto i datum
Stellenbosch, Južnoafrička Republika, 07.04.2014. - 11.04.2014

Vrsta sudjelovanja
Poster

Vrsta recenzije
Nije recenziran

Ključne riječi
nanofillers; compatibilizers; PLA/LDPE blends

Sažetak
Carefully chosen commercial nanofillers: silica (SiO2) and precipitated calcium carbonate (CaCO3), were used as compatibilizers in immiscible polylactide/low-density polyethylene (PLA/LDPE) blend. The general aim of this paper is to investigate the possibilities of replacing the standard commercial plastics such as LDPE based on non-renewable mineral oil resources with the biodegradable renewable polymer PLA in compatibilized PLA/LDPE blends for the use in packaging industry. The calculations of the minimal interfacial energy and optimal wetting abilities indicated SiO2 filler as a better potential compatibilizer, than CaCO3, for a given PLA/LDPE blend, due to its preferential localization at the interface. Commercial CaCO3 nanofiller showed less efficacy which in PLA/LDPE blend caused the heterogeneous surface of failure with the sign of phase de-bonding followed by visible plastic deformations that lower the strength at break of incompatible systems, what is in correlation with the high interfacial energy and preferential filler localization in one of the phases (LDPE) and not at the interface. The decreased size of dispersed domain and fine morphology in PLA/LDPE/SiO2 blend demonstrates that SiO2 can improve the compatibility between PLA and LDPE phases, and as a consequence increase toughness and crystallinity.

Izvorni jezik
Engleski

Znanstvena područja
Kemijsko inženjerstvo

POVEZANOST RADA