Naslov
Hybrid organic-inorganic POM's of Lindqvist and Keggin type

Autori
Pavlović, Gordana ; Cindrić, Marina ; Vrdoljak, Višnja

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, pp prezentacija, ostalo

Skup
1. Europska konferenciji o polioksometalatnoj kemiji u molekularnoj nanoznanosti

Mjesto i datum
Tenerife, Španjolska, 16.05.2013. - 19.05.2013

Vrsta sudjelovanja
Predavanje

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
aroylhydrazone ligands; cis-dioxomolybdenum(VI) building blocks; polyoxomolybdates

Sažetak
The last ten years one of the scientific interest of our group is the synthesis and characterization of hybrid organic-inorganic compounds based on POMs. Modification and functionalization of MoxOyn– or MoxMyOzn– with organic ligands such as peptides, amino acids, Schiff base derivatives or aroylhydrazones has been exploited to achieve more desirable properties. The prepared POMs were screened for the possible antiproliferative activity and some of them were used in catalytic studies as (pre)catalysts for epoxidation of cyclooctene without solvent. The prepared and examined POMs were of Lindqvist type, {; ; Mo6O19}; ; 2–, Keggin type, [(VIV, VV, Mo10)VO40]6– or -[Mo8O26]4– and α-[Mo8O26]4–.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA