Pregled bibliografske jedinice broj: 70621
Square-wave voltammetry of decamethylferrocene at the three-phase junction organic liquid˝aqueous solution˝graphite
Square-wave voltammetry of decamethylferrocene at the three-phase junction organic liquid˝aqueous solution˝graphite // Collection of Czechoslovak chemical communications, 66 (2001), 434-444 (međunarodna recenzija, članak, znanstveni)
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Naslov
Square-wave voltammetry of decamethylferrocene at the three-phase junction organic liquid˝aqueous solution˝graphite
Autori
Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj ; Scholz, Fritz
Izvornik
Collection of Czechoslovak chemical communications (0010-0765) 66
(2001);
434-444
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
ion transfer; square-wave voltammetry; three-phase junction; nitrobenzene; decamethylferrocene
Sažetak
Drops of nitrobenzene and 1,2-dichloroethane containing solely 0.1 mol/L decamethylferrocene (dmfc) are attached to the surface of a paraffin-impregnated graphite electrode and immersed into various aqueous electrolytes. The oxidation of dmfc and the reduction of the cation dmfc+ are enabled by the simultaneous transfers of anions between the aqueous electrolyte and the organic solvents. A square-wave voltammetry of this reaction is reported. A linear relationship is observed between the peak potentials of dmfc and the standard Galvani potential differences of the anions, and the influence of anion concentration on this straight line is explained.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
