Naslov
Synthesis and characterization of alkylated trinitromethyl- and fluorodinitromethyl-tetrazoles

Autori
Feierfeil, Johannes ; Kettner, Marcos ; Klapotke, Thomas ; Sućeska, Muhamed ; Wunder, Swetlana

Vrsta, podvrsta i kategorija rada
Radovi u zbornicima skupova, cjeloviti rad (in extenso), ostalo

Izvornik
Proceedings of the 17th Seminar on "New Trends in Research of Energetic Materials" / Pachman, Jiri ; Šelešovsky, Jakub ; Matyaš, Robert - Pardubice : University of Pardubice, 2014, 738-753

ISBN
978-80-7395-770-4

Skup
17th Seminar on New Trends in Research of Energetic Materials

Mjesto i datum
Pardubice, Češka Republika, 09.04.2014. - 11.04.2014

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
Tetrazoles; polynitro compounds; sensitivities; thermal analysis; structure elucidation; amination; secondary explosives; energetic performance; crystal structure

Sažetak
Here we report about the synthesis of 2-(2-nitro-2-azapropyl)-5-(trinitro-methyl)-tetrazole and analogue 2-(2-nitro-2-azapropyl)-5-(fluorodinitromethyl)-tetrazole. The prepared materials were characterized thoroughly including single crystal X-ray diffraction and differential scanning calorimetry measurements. The sensitivities towards impact, friction and electrostatic discharge were determined. In addition, the performance of the materials was calculated using the EXPLO5 computer code, with heats of formation calculated at the CBS-4M level of theory and densities obtained from pycnometer measurements.

Izvorni jezik
Engleski

Znanstvena područja
Kemija, Kemijsko inženjerstvo

POVEZANOST RADA