Pregled bibliografske jedinice broj: 696280
Formation and characterization of thioglycolic acid–silver cluster complexes
Formation and characterization of thioglycolic acid–silver cluster complexes // Dalton transactions, 42 (2013), 23; 8328-8333 doi:10.1039/C3DT50485A (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 696280 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Formation and characterization of thioglycolic acid–silver cluster complexes
Autori
Bellina, Bruno ; Antoine, Rodolphe ; Broyer, Michel ; Gell, Lars ; Sanader, Željka ; Mitrić, Roland ; Bonačić-Koutecký, Vlasta ; Dugourd, Philippe
Izvornik
Dalton transactions (1477-9226) 42
(2013), 23;
8328-8333
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
fragmentation; thioglycolic acid; silver cluster
Sažetak
Gas phase reactivity observed in an ion trap was used to produce silver clusters protected with thioglycolic acid. Fragmentation pathways as well as optical properties were explored experimentally and theoretically. Sequential losses of SCH2 and CO2 in the ion trap lead to redox reactions with charge transfers between the metal part and the carboxylate and thiolate groups. This allows us to control the number of electrons in the metallic subunit and thus optical properties of the complexes. The presented formation process can be used as a prototype for tuning optical and chemical properties of ligated metal clusters by varying the number of confined electrons within the metallic subunit.
Izvorni jezik
Engleski
Znanstvena područja
Fizika
POVEZANOST RADA
Ustanove:
Prirodoslovno-matematički fakultet, Split,
Sveučilište u Splitu
Profili:
Željka Sanader Maršić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE
