Pregled bibliografske jedinice broj: 674069
Generation of the Parent Allyl Cation in a Superacid Cryogenic Matrix
Generation of the Parent Allyl Cation in a Superacid Cryogenic Matrix // Angewandte Chemie. International edition, 33 (1994), 4; 448-451 doi:10.1002/anie.199404481 (međunarodna recenzija, članak, znanstveni)
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Naslov
Generation of the Parent Allyl Cation in a Superacid Cryogenic Matrix
Autori
Buzek, Peter ; Schleyer, Paul von R. ; Vančik, Hrvoj ; Mihalić, Zlatko ; Gauss, Jürgen
Izvornik
Angewandte Chemie. International edition (1433-7851) 33
(1994), 4;
448-451
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
superacids; allyl cation; matrix isolation
Sažetak
By using cyclopropyl bromide as precursor, the allyl cation C3Hmath image can be generated at low temperature in an SbF5 matrix and observed by IR spectroscopy ; the experimental IR spectrum agrees well with that computed by ab initio methods. Characterization by 13C NMR spectroscopy failed, but the 13C NMR chemical shifts of this and other allyl cations could be predicted accurately for the first time by the GIAO/MP-2 method.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
