Pregled bibliografske jedinice broj: 653415
Mechanochemically induced cross-dimerizations of nitrosobenzenes. Kinetics and solid-state isotope effects
Mechanochemically induced cross-dimerizations of nitrosobenzenes. Kinetics and solid-state isotope effects // Journal of physical organic chemistry, 27 (2014), 3; 177-182 doi:1002/poc.3256 (međunarodna recenzija, članak, znanstveni)
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Naslov
Mechanochemically induced cross-dimerizations of nitrosobenzenes. Kinetics and solid-state isotope effects
Autori
Maganjić, Ana ; Šolić, Ivan ; Milovac, Srđan ; Halasz, Ivan ; Biljan, Ivana ; Vančik, Hrvoj
Izvornik
Journal of physical organic chemistry (0894-3230) 27
(2014), 3;
177-182
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
solid-state reaction mechanism; mechanochemistry; nitroso compounds; azodioxides; solid-state isotope effects
Sažetak
Mechanical treatment (milling) of crystals of aromatic nitroso dimers (azodioxides) induces their dissociation and cross-dimerizations. The mechanisms of these processes are discussed on the basis of kinetic studies and the solid-state 15N kinetic isotope effect, which is measured for the first time. By comparison with analogous processes in co-crystals and in melts, it appears that the reactions follow similar mechanism in which the surface deformations play the crucial role. The system can also be used as a model for more general conceptual study of solid-state reaction mechanisms.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
119-1191342-1334 - Reakcije organskih spojeva u čvrstom stanju: mehanizmi i supramolekulski inženje (Vančik, Hrvoj, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
