Pregled bibliografske jedinice broj: 638609
Cyclic voltammetry of the second order CE mechanism at the thin mercury film covered stationary planar electrode
Cyclic voltammetry of the second order CE mechanism at the thin mercury film covered stationary planar electrode // Journal of the chilean chemical society, 58 (2013), 4; 2191-2195 doi:10.4067/S0717-97072013000400062 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 638609 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Cyclic voltammetry of the second order CE mechanism at the thin mercury film covered stationary planar electrode
Autori
Lovrić, Milivoj
Izvornik
Journal of the chilean chemical society (0717-9324) 58
(2013), 4;
2191-2195
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
cyclic voltammetry; metal complexes; kinetics of chemical reaction; CE mechanism
Sažetak
A theoretical model of electrode reaction influenced by the kinetics of complex formation and dissociation is developed for cyclic voltammetry. It is assumed that the electro-reductions of free metal ions and the complex are reversible and totally irreversible, respectively, and that the ligand is not present in great excess. The results show that the stripping peak current and potential depend on the relative bulk concentration of ligand, particularly within the range 1 < < 3, and on the rate constant of complex formation.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Profili:
Milivoj Lovrić
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
