Pregled bibliografske jedinice broj: 63355
Acidity of phenylcyclobutene: experimental and gas phase results
Acidity of phenylcyclobutene: experimental and gas phase results // Programme and Abstracts of the II. ACIS-CHEM Meeting 2000
Zagreb: Institut Ruđer Bošković, 2000. str. P14-P14 (poster, međunarodna recenzija, sažetak, znanstveni)
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Naslov
Acidity of phenylcyclobutene: experimental and gas phase results
Autori
Glasovac, Zoran ; Kass, Steven R. ; Eckert-Maksić, Mirjana
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
Programme and Abstracts of the II. ACIS-CHEM Meeting 2000
/ - Zagreb : Institut Ruđer Bošković, 2000, P14-P14
Skup
ACIS-CHEM Meeting (2 ; 2000)
Mjesto i datum
Brijuni, Hrvatska, 03.09.2000. - 06.09.2000
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
gas phase acidity; phenylcyclobutene; ab initio calculations
Sažetak
Results on determination of intrinsic acidity of phenylcyclobutene will be presented. Gas phase acidity was determined using bracketing technique in FT-MS ICR spectrometer. In addition, proton affinities calculated with high level ab initio MP2/6-31+G(d) and DFT B3LYP/6-31+G(d) will be compared with experimental results. To evaluate influence of phenyl moiety on cyclobutenyl anions (position a and b) and parent cyclobutenyl anion were investigated. Difference in acidities of phenylcyclobutene and cyclobutene itself will be discussed in terms of geometric and electronic structure changes upon substitution by phenyl group.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
