Diiodo-3, 4, 5, 6-tetrahydropyrimidinium-2-thiolato-S-mercury(II)

Matković-Čalogović, Dubravka; Popović, Zora; Pavlović, Gordana; Soldin, Željka; Giester, Gerald

Pregled bibliografske jedinice broj: 62693

Diiodo-3, 4, 5, 6-tetrahydropyrimidinium-2-thiolato-S-mercury(II)

Matković-Čalogović, Dubravka; Popović, Zora; Pavlović, Gordana; Soldin, Željka; Giester, Gerald

Diiodo-3, 4, 5, 6-tetrahydropyrimidinium-2-thiolato-S-mercury(II) // Acta Crystallographica C, Crystal Structure Communications, C57 (2001), -; 409-411 (međunarodna recenzija, članak, znanstveni)

CROSBI ID: 62693 Za ispravke kontaktirajte CROSBI podršku putem web obrasca

Naslov
Diiodo-3, 4, 5, 6-tetrahydropyrimidinium-2-thiolato-S-mercury(II)

Autori
Matković-Čalogović, Dubravka ; Popović, Zora ; Pavlović, Gordana ; Soldin, Željka ; Giester, Gerald

Izvornik
Acta Crystallographica C, Crystal Structure Communications (0108-2701) C57 (2001); 409-411

Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni

Ključne riječi
mercury(II) iodide; 3; 4; 5; 6-terahydropyrimidine-2-thione; crystal structure

Sažetak
The reaction of 3, 4, 5, 6-tetrahydropyrimidine-2-thione (H_4pymtH) with mercury(II) iodide in methanol in a 1:1 molar ratio resulted in the formation of single crystals of the title compound, [Hg(C_4H_8N_2S)I_2 ]. The Hg atom is coordinated by one S atom from H_4pymtH at 2.456 (2) A and by two I atoms at distances of 2.6872 (7) and 2.7044 (6) A , and has a characteristic deformed trigonal coordination geometry. The molecule has crystallographic m symmetry but the Hg atom is disordered above and below the mirror plane.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

POVEZANOST RADA

Projekti:
119408

Ustanove:
Prirodoslovno-matematički fakultet, Zagreb

Profili:

Zora Popović (autor)