Naslov
Synthesis and x-ray structural analysis of 1, 6-disubstituted diamantanes

Autori
Šekutor, Marina ; Molčanov, Krešimir ; Mlinarić-Majerski, Kata ; Glaser, Robert

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni

Izvornik
23. hrvatski skup kemičara i kemijskih inženjera : knjiga sažetaka = 23. Croatian meeting of chemists and chemical engineers : book of abstracts / Hadžiev, Andrea ; Blažeković, Zdenko - Zagreb : Hrvatsko društvo kemijskih inženjera i tehnologa (HDKI), 2013, 129-129

ISBN
978-953-6894-50-5

Skup
23. hrvatski skup kemičara i kemijskih inženjera = 23. Croatian meeting of chemists and chemical engineers

Mjesto i datum
Osijek, Hrvatska, 21.04.2013. - 24.04.2013

Vrsta sudjelovanja
Poster

Vrsta recenzije
Domaća recenzija

Ključne riječi
rendgenska strukturna analiza ; 1 ; 6-disubstituirani diadamantani
(x-ray structural analysis ; 1 ; 6-disubstituted diadamananes)

Sažetak
Adamantane polycyclic compounds have recently found their use in studies of molecular recognition and self-assembly properties of cucurbit[n]uril macrocycles.[1] In these complexes the highly selective binding interactions with cationic species are driven by a combination of ion-dipole interactions, hydrogen bonds and the hydrophobic effect. We recently synthesized various 2, 6-diaminoadamantane salts [2] with the aim of studying their interactions with cucurbit[n]uril family of compounds and in the continuation of this research we turned our attention to diamantane.[3] Some 1, 6-disubstituted derivatives of diamantane are already known in the literature, [4] but we sought to synthesize the positively charged 1, 6-diamine salts such as 4 and 5 for further use in the binding studies. Herein we report the synthesis and crystal structure determination of a number of 1, 6- disubstituted diamantanes.

Izvorni jezik
Engleski

Znanstvena područja
Kemija

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