Pregled bibliografske jedinice broj: 609658
Theory of square-wave voltammetry of kinetically controlled two-step electrode reactions
Theory of square-wave voltammetry of kinetically controlled two-step electrode reactions // Croatica chemica acta, 85 (2012), 4; 569-575 doi:10.5562/cca2126 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 609658 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Theory of square-wave voltammetry of kinetically controlled two-step electrode reactions
Autori
Lovrić, Milivoj ; Komorsky-Lovrić, Šebojka
Izvornik
Croatica chemica acta (0011-1643) 85
(2012), 4;
569-575
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Square-wave voltammetry; kinetics of electrode reaction; two-step electrode reaction; intermediate; standard rate constant.
Sažetak
An influence of electron transfer kinetics on square-wave voltammograms of two-step electrode reaction is investigated theoretically. A phenomenon of “kinetic burden” of potential inversion is described for the case of equal kinetic parameters. A linear relationship between standard rate constant and the difference between standard potentials of the second and the first charge transfers is demonstrated for the reactions with thermodynamically unstable intermediate.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
