Pregled bibliografske jedinice broj: 6055
The role of molar volume of the organic solvents in the swelling system EPDM vulcanizate/solvent
The role of molar volume of the organic solvents in the swelling system EPDM vulcanizate/solvent // Die angewandte makromolekulare Chemie, 242 (1996), 1; 85-96 doi:10.1002/apmc.1996.052420105 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 6055 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
The role of molar volume of the organic solvents in the swelling system EPDM vulcanizate/solvent
Autori
Hrnjak-Murgić, Zlata ; Jelenčić, Jasenka ; Bravar, Mladen
Izvornik
Die angewandte makromolekulare Chemie (0003-3146) 242
(1996), 1;
85-96
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
dicumyl peroxide ; EPDM ; molar volume ; solvents ; swelling ; vulcanizates
Sažetak
Eight samples of poly(ethylene-co-propylene-co-diene)(EPDM, containing 55 wt.-% ethylene) were vulcanized with 0, 5-8, 0 phr dicumyl peroxide. The influence of molar volumes V1 of cyclohexane, hexane, heptane, iso-octane, tetrachloromethane, carbon disulfide, xylene, benzene, toluene, tetrahydrofuran, trichloromethane and chlorobenzene on the swelling intensity of the EPDM vulcanizates was studied, and it was found that regardless of the solubility parameters, polarity, dielectric constants, acidity or basicity of solvents, a linear relationship exists between V1 and number of moles of solvent in the gels, n1. With increase of V1, n1 decreases.
Izvorni jezik
Engleski
Znanstvena područja
Kemijsko inženjerstvo
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
