Pregled bibliografske jedinice broj: 576505
Theory of square-wave voltammetry of two electron reduction with the intermediate that is stabilized by complexation
Theory of square-wave voltammetry of two electron reduction with the intermediate that is stabilized by complexation // Electrochimica acta, 69 (2012), 60-64 doi:10.1016/j.electacta.2012.02.063 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 576505 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Theory of square-wave voltammetry of two electron reduction with the intermediate that is stabilized by complexation
Autori
Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj
Izvornik
Electrochimica acta (0013-4686) 69
(2012);
60-64
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
square-wave voltammetry ; two electron reaction ; complexation ; theory
Sažetak
An influence of complexation of reactant and intermediate on square-wave voltammograms of reversible, two-step electrode reaction is analyzed theoretically. The potentials of the first and the second peak of the split net response depend on stability constants of complexes, the standard potentials of individual electron transfers and on the concentration of ligand: Ep, 1 - = (RT / F)(ln - ln ) and Ep, 2 - = (RT / F) ln , where = 1 + + + … and = 1 + + + …
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
MZOS-098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
