Pregled bibliografske jedinice broj: 575501
Structural investigation of aroylhydrazones in dimethylsulphoxide/water mixtures
Structural investigation of aroylhydrazones in dimethylsulphoxide/water mixtures // Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 95 (2012), 347-353 doi:10.1016/j.saa.2012.03.086 (međunarodna recenzija, članak, znanstveni)
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Naslov
Structural investigation of aroylhydrazones in dimethylsulphoxide/water mixtures
Autori
Galić, Nives ; Dijanošić, Adriana ; Kontrec, Darko ; Miljanić, Snežana
Izvornik
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy (1386-1425) 95
(2012);
347-353
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
aroylhydrazones; FT IR; ATR; Raman; NMR; UV-Vis
Sažetak
Molecular structures of aroylhydrazones derived from salycilaldehyde, o-vanilin and nicotinic acid hydrazide in DMSO and DMSO/H2O mixtures have been studied by NMR, UV-Vis, ATR and Raman spectroscopy. The addition of water to the system did not induce tautomeric conversion of the existing form constituted of the ketoamino hydrazide part and the enolimino aldehyde part, but it was involved in formation of hydrated molecules. Vibrational spectra (ATR and Raman) clearly indicated hydrogen bonding of the studied hydrazones through the carbonyl, amino and hydroxyl groups with water molecules. Increasing the water content conversion from E to Z isomer was not observed.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
119-1191342-1083 - Interakcije i dizajn bioaktivnih molekula (Novak, Predrag, MZOS ) ( CroRIS)
119-1191342-2959 - Spektroskopska analiza nezasićenih sustava i spojeva metala (Miljanić, Snežana, MZOS ) ( CroRIS)
119-1191342-2960 - Elektroliti i koordinacijske reakcije u otopini (Tomišić, Vladislav, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
- MEDLINE