Pregled bibliografske jedinice broj: 575121
Theory of square-wave voltammetry of two electron reduction with the adsorption of intermediate
Theory of square-wave voltammetry of two electron reduction with the adsorption of intermediate // International Journal of Electrochemistry, 2012 (2012), 1-7 doi:10.1155/2012/596268 (podatak o recenziji nije dostupan, članak, znanstveni)
CROSBI ID: 575121 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Theory of square-wave voltammetry of two electron reduction with the adsorption of intermediate
Autori
Lovrić, Milivoj ; Komorsky-Lovrić, Šebojka
Izvornik
International Journal of Electrochemistry (2090-3529) 2012
(2012);
1-7
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Square-wave voltammetry ; two electron electrode reaction ; adsorption of intermediate ; theory of EE mechanism
Sažetak
Thermodynamically unstable intermediate of fast and reversible two electron electrode reaction can be stabilized by the adsorption to the electrode surface. In square-wave voltammetry of this reaction mechanism the split response may appear if the electrode surface is not completely covered by the adsorbed intermediate. The dependence of the difference between the net peak potentials of the prepeak and postpeak on the square-wave frequency is analysed theoretically. This relationship can be used for the estimation of adsorption constant.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Emerging Sources Citation Index (ESCI)
