Pregled bibliografske jedinice broj: 550667
Isoabsorption and spectrometric studies of optical absorption edge in Cu_6AsS_5I superionic crystal
Isoabsorption and spectrometric studies of optical absorption edge in Cu_6AsS_5I superionic crystal // Journal of physics and chemistry of solids, 72 (2011), 12; 1419-1422 doi:10.1016/j.jpcs.2011.08.012 (međunarodna recenzija, članak, znanstveni)
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Naslov
Isoabsorption and spectrometric studies of optical absorption edge in Cu_6AsS_5I superionic crystal
Autori
Studenyak, I.P. ; Kayla, M.I. ; Kranjčec, Mladen ; Kokhan, O.P ; Minets, Yu.V.
Izvornik
Journal of physics and chemistry of solids (0022-3697) 72
(2011), 12;
1419-1422
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
superionic conductors; phase transitions; optical properties
Sažetak
Cu_6AsS_5I single crystals were grown using chemical vapour transport method. Two low-temperature phase transitions (PT) are observed from isoabsorption studies: a first-order PT at ТІ=153±1 K and a second-order PT in the temperature interval ТІI=260–280 K. At low temperatures and high absorption levels an excitonic absorption band was revealed in the range of direct optical transitions. At Т>ТІ, the absorption edge has an exponential form and a characteristic Urbach bundle is observed. The influence of the cationic P->As substitution on the parameters of the Urbach absorption edge, parameters of exciton-phonon interaction, and phase transitions temperatures is studied.
Izvorni jezik
Engleski
Znanstvena područja
Fizika
POVEZANOST RADA
Projekti:
160-0982886-0873 - Nano-efekti i utjecaji neuređenosti u materijalima za ioniku čvrstog stanja (Kranjčec, Mladen, MZOS ) ( CroRIS)
Ustanove:
Geotehnički fakultet, Varaždin
Profili:
Mladen Kranjčec
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus