Pregled bibliografske jedinice broj: 531957
Epoxidation Processes by Pyridoxal Dioxomolybdenum(VI) (Pre)Catalysts Without Organic Solvent
Epoxidation Processes by Pyridoxal Dioxomolybdenum(VI) (Pre)Catalysts Without Organic Solvent // Advanced synthesis & catalysis, 353 (2011), 16; 2910-2914 doi:10.1002/adsc.201100439 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 531957 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Epoxidation Processes by Pyridoxal Dioxomolybdenum(VI) (Pre)Catalysts Without Organic Solvent
Autori
Pisk, Jana ; Agustin, Dominique ; Vrdoljak, Višnja ; Poli, Rinaldo
Izvornik
Advanced synthesis & catalysis (1615-4150) 353
(2011), 16;
2910-2914
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
epoxidation; molybdenum; pyridoxal ligands; homogeneous catalysis; solvent-free
Sažetak
Molybdenum(VI) pyridoxal thiosemicarbazonato complexes have proved to be efficient catalysts in olefin epoxidation of cyclooctene by aqueous TBHP in absence of organic solvent. High activity and selectivity have been obtained with a catalyst loading of just 0.05% molybdenum in the case of one mononuclear (pre)catalyst (TOF 3360 h–1) under solvent-free conditions. The influence of methanol on activity and selectivity has been studied.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
119-1191342-1082 - Novi kompleksni spojevi i materijali-kemijski i biološki katalizatori (Cindrić, Marina, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
