Pregled bibliografske jedinice broj: 524096
Pd-porphyrin functionalized ionic liquid-modified mesoporous SBA-15 : An efficient and recyclabe catalyst for solvent-free Heck reaction
Pd-porphyrin functionalized ionic liquid-modified mesoporous SBA-15 : An efficient and recyclabe catalyst for solvent-free Heck reaction // Materials research bulletin, 45 (2010), 11; 1648-1653 doi:10.1016/j.materresbull.2010.07.006 (međunarodna recenzija, članak, znanstveni)
CROSBI ID: 524096 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Pd-porphyrin functionalized ionic liquid-modified mesoporous SBA-15 : An efficient and recyclabe catalyst for solvent-free Heck reaction
Autori
Zhang, Jing ; Zhao, Guo-Feng ; Popović, Zora ; Lu, Young ; Liu, Ye
Izvornik
Materials research bulletin (0025-5408) 45
(2010), 11;
1648-1653
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
composites; organic compounds; chemical synthesis; catalytic properties
Sažetak
The Pd-porphyrine functionalized ionic liquid could be covalently anchored in the channels of mesophorous SBA-15 through ion-pair electrostatic interaction between imidazolium-cationic and Pd-porfpyrin-anionic moieties. Such modified SBA-15 materials were prepared successfully via a post-synthesis (surface sol-gel polymerization) or a one-pot sol-gel procedure, which were characterized by powder X-ray diffraction, UV-visible spectroscopy, Fourier transform infrared spectroscopy, N2 sorption, elemental analysis, and transmission electron microscopy. The modifies SBA-15 materials are efficient and recyclable catalysts for cross-coupling of aryl iodides or activated aryl bromides with ethyl acrylate without loss of Pd leaching vevn after 9 runs.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
119-1193079-1332 - Kemija metalnih kompleksa u reakcijama od biološkog značaja i novim materijalima (Popović, Zora, MZOS ) ( CroRIS)
Ustanove:
Prirodoslovno-matematički fakultet, Zagreb
Profili:
Zora Popović
(autor)
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus