Pregled bibliografske jedinice broj: 522750
Theory of square-wave voltammetry of two-step electrode reaction with kinetically stabilized intermediate
Theory of square-wave voltammetry of two-step electrode reaction with kinetically stabilized intermediate // Journal of electroanalytical chemistry, 660 (2011), 1; 22-25 doi:10.1016/j.jelechem.2011.05.026 (međunarodna recenzija, članak, znanstveni)
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Naslov
Theory of square-wave voltammetry of two-step electrode reaction with kinetically stabilized intermediate
Autori
Komorsky-Lovrić, Šebojka ; Lovrić, Milivoj
Izvornik
Journal of electroanalytical chemistry (1572-6657) 660
(2011), 1;
22-25
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
two-step electrode reaction ; EE mechanism ; kinetics of electrode reaction ; square-wave voltammetry
Sažetak
Square-wave voltammograms of quasireversible EE mechanism with thermodynamically unstable intermediate may consist either of a single peak, or of two peaks if the second electron transfer appears quasireversible at the lowest frequency and irreversible at the highest frequency. The development of the second peak depends on the critical dimensionless kinetic parameter which was calculated in this paper. This parameter can be used for the estimation of standard rate constant of the second electrode reaction.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Current Contents Connect (CCC)
- Web of Science Core Collection (WoSCC)
- Science Citation Index Expanded (SCI-EXP)
- SCI-EXP, SSCI i/ili A&HCI
- Scopus
