Pregled bibliografske jedinice broj: 518560
Mechanochemical Synthesis of Zinc and Cadmium Metal-Organic Frameworks – The Story of Dimensionality and Solid-State Reactivity
Mechanochemical Synthesis of Zinc and Cadmium Metal-Organic Frameworks – The Story of Dimensionality and Solid-State Reactivity // XX International Conference on the Chemistry of the Organic Solid State / Guru Row, T. N. (ur.).
Bangalore: Indian Institute of Science, 2011. (poster, međunarodna recenzija, sažetak, znanstveni)
CROSBI ID: 518560 Za ispravke kontaktirajte CROSBI podršku putem web obrasca
Naslov
Mechanochemical Synthesis of Zinc and Cadmium Metal-Organic Frameworks – The Story of Dimensionality and Solid-State Reactivity
Autori
Štrukil, Vjekoslav ; Fábián, László ; Reid, David G. ; Duer, Melinda J. ; Jackson, Graham J. ; Eckert-Maksić, Mirjana ; Friščić, Tomislav
Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, znanstveni
Izvornik
XX International Conference on the Chemistry of the Organic Solid State
/ Guru Row, T. N. - Bangalore : Indian Institute of Science, 2011
Skup
XX International Conference on the Chemistry of the Organic Solid State
Mjesto i datum
Bangalore, Indija, 26.06.2011. - 30.06.2011
Vrsta sudjelovanja
Poster
Vrsta recenzije
Međunarodna recenzija
Ključne riječi
mechanosynthesis; environmentally-friendly synthesis; metal-organic frameworks
Sažetak
Mechanical treatment of chemicals by simply grinding them together in a ball mill has been identified as a clean and environmentally-friendly synthetic methodology that meets the requirements of green chemistry (1). As such, mechanochemistry has recently opened new opportunities for the design and construction of new materials, e.g. coordination polymers, pharmaceutical derivatives and porous metal-organic frameworks (MOFs) (2). We envisage that, in combination with modern solid-state analytical methods, automated ball-milling can provide an almost entirely solvent-free route from the synthesis and analysis to the full structural characterisation of a product. In this contribution we present a mechanochemical approach for the selective synthesis of simple metal-organic frameworks. Solid-state methodology based on the concept of liquid-assisted grinding (LAG) (3) allows a rapid screening for different stoichiometric compositions of MOFs with cyanoguanidine as a heteroditopic ligand (4). The products obtained by mechanosynthesis have been further characterised by solid-state analytical tools such as FTIR-ATR, solid-state NMR and structure solution from X-ray powder diffraction data, eliminating the need for bulk solvents in our research laboratory.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
Napomena
CrystEngComm nagrada za najbolji poster
POVEZANOST RADA
Projekti:
098-0982933-2920 - Organski i bioorganski procesi u osnovnom i elektronski pobuđenim stanjima (Maksić, Mirjana, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
