Pregled bibliografske jedinice broj: 515640
Theory of square-wave voltammetry of two-step electrode reaction using an inverse scan direction
Theory of square-wave voltammetry of two-step electrode reaction using an inverse scan direction // International Journal of Electrochemistry, 2011 (2011), 538341, 6 doi:10.4061/2011/538341 (međunarodna recenzija, članak, znanstveni)
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Naslov
Theory of square-wave voltammetry of two-step electrode reaction using an inverse scan direction
Autori
Lovrić, Milivoj ; Komorsky-Lovrić, Šebojka
Izvornik
International Journal of Electrochemistry (2090-3529) 2011
(2011);
538341, 6
Vrsta, podvrsta i kategorija rada
Radovi u časopisima, članak, znanstveni
Ključne riječi
Square-wave voltammetry ; two-step electrode reaction ; theory of quasireversible EE mechanism
Sažetak
A theory of square-wave voltammetry of two-step electrode reaction with kinetically controlled electron transfers is developed and a special case of thermodynamically unstable intermediate is analyzed. If the first reaction step is reversible and the second one is quasireversible, the response splits into two peaks if the scan direction is inverted. The separation of these peaks increases with frequency.
Izvorni jezik
Engleski
Znanstvena područja
Kemija
POVEZANOST RADA
Projekti:
098-0982904-2907 - Elektroanalitička istraživanja mikrokristala i tragova otopljenih supstanci (Lovrić, Milivoj, MZOS ) ( CroRIS)
Ustanove:
Institut "Ruđer Bošković", Zagreb
Citiraj ovu publikaciju:
Časopis indeksira:
- Web of Science Core Collection (WoSCC)
- Emerging Sources Citation Index (ESCI)