Naslov
Fotoinducirana H-apstrakcija kod N-(4-homoadamantil)ftalimida
(Photoinduced H-abstraction in N-(4-homoadamantyl)phthalimide)

Autori
Cindro, Nikola ; Horvat, Margareta ; Mlinarić-Majerski, Kata ; Griesbeck, Axel G. ; Basarić, Nikola

Vrsta, podvrsta i kategorija rada
Sažeci sa skupova, sažetak, ostalo

Izvornik
XXII. hrvatski skup kemičara i kemijskih inženjera : knjiga sažetaka / - Zagreb, 2011, 122-122

Skup
Hrvatski skup kemičara i kemijskih inženjera (22 ; 2011)

Mjesto i datum
Zagreb, Hrvatska, 13.02.2011. - 16.02.2011

Vrsta sudjelovanja
Poster

Vrsta recenzije
Međunarodna recenzija

Ključne riječi
arili; fotokemija; ftalimid
(aryl; photochemistry; phthalimide;)

Sažetak
The photochemistry of different alkyl- and arylphthalimides has been in the focus of interest of researchers for a long time [1]. Since photoreactivity of phthalmide derivatives can generally be tuned by irradiation conditions and addition of specific reagents, often giving complex azaheterocycles, it can be applied as a key step in organic synthesis. In our previous studies we have found that different adamantylphthalimide derivatives in the triplet excited state undergo photoinduced H-abstraction and give new polycyclic structures [2]. Herein we present synthesis and photochemistry of novel N-(4-homoadamantyl)phthalimide (1). Photoreaction of 1 delivers three products 2, syn-3 and anti-3, that were isolated and characterized by spectroscopic methods. Photochemical reaction mechanism for the formation of 2, syn-3 and anti-3 will be presented.

Izvorni jezik
Hrvatski

Znanstvena područja
Kemija

POVEZANOST RADA